Figure 5 | Scientific Reports

Figure 5

From: Coordinative Alignment of Chiral Molecules to Control over the Chirality Transfer in Spontaneous Resolution and Asymmetric Catalysis

Figure 5

Different processes of catalysts assembly and asymmetric cycloaddition transformations. (a) Ag(I)-MOFs formed via the spontaneous crystallization were used for the asymmetric 1,3-dipolar cycloaddition, showing the random chirality of the product. (b) Ag(I)-MOFs formed via the induction crystallization were used for the asymmetric 1,3-dipolar cycloaddition, showing the catalyst-determined chirality of the product. (c) The tandem process of spontaneous resolution and the asymmetric 1,3-dipolar cycloaddition, showing the substrate-determined chirality of the product.

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