Table 1 For each sample, the integrated thermal activation paramter \({{D}}_{{\rm{\Sigma }}}^{\ast }\) is shown in the second column, followed by the aggregate time spent at each 1000 °C, 1100 °C, and 1200 °C. Using the \({D}_{{\rm{\Sigma }}}^{\ast }\) parameter for each sample, we calculate equivalent activation times (t eq ) if the sample had sat at a single temperature of either 1100 °C or 1200 °C. The next two columns provide single dopant bulk and surface diffusion lengths using E a  = 3.5 eV12 for 3D, E a  = 0.94 eV11 for 2D and D0 = 3.85 cm2/s19 for both bulk and surface diffusion. Finally, the equivalent time at 1100 °C is used to estimate the spreading of the implanted dopants “edge” using an online diffusion calculator, corresponding to a dopant density of 3.8 × 1018 cm3.

From: STM patterned nanowire measurements using photolithographically defined implants in Si(100)

Sample

\({{\boldsymbol{D}}}_{{\boldsymbol{\Sigma }}}^{{\boldsymbol{\ast }}}\)

Total time (s)a

t eq (min)b

Diffusion length (μm)b

l c (μm)c

1000 °C

1100 °C

1200 °C

1100 °C

1200 °C

l 3D

l 2D

D1

0.084 ± 0.003

60

0

0

0.10

0.01

0.02

2.09 × 103

D2

2.5 ± 0.3

55

48

23

2.81

0.38

0.10

3.99 × 103

0.23

D3

5.1 ± 0.4

69

54

45

5.86

0.79

0.14

5.73 × 103

0.34

D4

6.1 ± 0.4

0

97

51

6.97

0.94

0.15

5.78 × 103

0.37

D5

7.5 ± 0.6

0

7

60

8.56

1.15

0.17

4.53 × 103

0.43

D6

9.1 ± 0.5

0

151

93

10.34

1.39

0.19

7.04 × 103

0.46

D7

26.2 ± 0.5

52

1816

23

29.95

4.03

0.32

16.08 × 103

0.78

  1. aThe total times reported for each sample for each temperature is the time that the sample reached 95% of the corresponding temperature and we estimate the uncertainty to be  ± 2 s. bRelative uncertainty for equivalent anneal time (t eq ) and the diffusion lengths (l3D, and l2D) are estimated as < 10%. cl c is the broadening of the critical concentration for metal-insulator transition relative to as implanted dopant profile due to annealing at 1100 °C for t = t eq time using publicly accessible dopant profile calculator20.