Table 2 Selected bond lengths (Å) and bond angles (°) for [H2F]2[Ni3F6(Fpy)12][SbF6]2.
Ni(1)-F(3) | 2.000(1) | N(1)-Ni(1)-N(1) | 180 |
|---|---|---|---|
Ni(1)-N(1) | 2.145(1) | N(1)-Ni(1)-N(2) | 91.22(5) |
Ni(1)-N(2) | 2.101(1) | N(1)-Ni(1)-F(3) | 91.56(5) |
H(1C)-F(3) | 1.392 | N(2)-Ni(1)-F(3) | 88.97(5) |
H(2C)-F(3) | 1.444 | Ni(1)-F(3)-H(1C) | 144.45 |
H(1C)-F(1C) | 0.96 | Ni(1)-F(3)-H(2C) | 153.49 |
H(2C)-F(2C) | 0.96 | C(1)-N(1)-C(5) | 117.2(2) |
F(1C)···F(3) | 2.352(1) | F(1)-C(1)-C(2) | 118.5(2) |
F(2C)···F(3) | 2.404(2) | F(1A)-Sb(1A)-F(2A) | 91.4(5) |
N(1)-C(1) | 1.334(2) | F(1A)-Sb(1A)-F(3A) | 90.4(5) |
N(1)-C(5) | 1.333(2) | Ni···Ni (intraplane) | 7.181(1) |
F(1)-C(2) | 1.348(3) | Ni···Ni (interplane) | 11.105(1) |
