Table 1 The collection of catalytic activities of non-metallocene chromium(III) complexes for the ethylene polymerization.

From: Oligomerization of 2-chloroallyl alcohol by 2-pyridinecarboxylate complex of chromium(III) - new highly active and selective catalyst

Complex

Temperature [°C]

Catalytic activity (g∙mmol−1∙h−1∙bar−1)

References

[Cr{2-[2-(diphenylphosphino)-1-(N-methylimidazol-2-yl) ethyl]-N-methy limidazole}Cl3]

100

108

24

[Cr{tris(N-methylimidazol-2-yl)methoxymethane}Cl3]

100

208

24

[Cr(1,3,5-triazacyclohexane)]Cl3

40

717

25

[(2,6-Me2Ph)2(nacnac)Cr (OEt2)CH2SiMe3] B(3,5-(CF3)2C6H3)4 (nacnac = 2,4-pentane-N,N’-bis(aryl)ketiminato)

75

228

26

CrMe[N(SiMe2CH2PPh2)2

300

500

1

[2,6-bis(imino)pyridyl]CrCl3

70

1000

27

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