Figure 3

(a) Scattering angle dependence of the Raman spectra of 5L 2H-SnS2 measured by using 2.33 eV (532 nm) excitation laser. Labels S (shear) and B (breathing) indicate the positions of shear and breathing modes resolved in 5L 2H-SnS2, respectively. (b) Schematics of interlayer in-plane shear and out-of-plane breathing modes. (c) Shear modes measured in cross polarization. (d) Shear and breathing modes measured in parallel polarization. The dashed curves are guides for the eye. (e) Peak positions as a function of number of layers. Solid curves are fitting results using the linear chain model.