Table 2 Summary of photovoltaic parameters and overlap parameters (J, S, S′, and OI) of TLSC systems with the different cyanine luminophores and Cy7-NHS (from ref 3). We note that only the OI accurately correlates to the scaling behavior measured and shown in Fig. 4.
Area (cm2) | Jsc (mAcm−2) | Int. Jsc (mAcm−2) | Voc (V) | FF (%) | PCE (%) | AVT (%) | CRI | J (μm3M−1) | S | S′ | OI | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
Cy7-NHS 3 | 4 | 1.2 ± 0.1 | 1.00 | 0.50 ± 0.01 | 66 ± 2 | 0.40 ± 0.03 | 87.7 | 91.0 | 1.49 | 4.07 | 1.84 | 27.9 |
Cy7-CA | 6.45 | 1.55 ± 0.05 | 0.96 | 0.47 ± 0.01 | 61 ± 1 | 0.44 ± 0.02 | 88.1 | 92.1 | 1.56 | 3.49 | 1.72 | 27.2 |
25.8 | 0.93 ± 0.02 | 0.49 ± 0.01 | 61 ± 1 | 0.28 ± 0.02 | ||||||||
Cy7-NEt2-I | 6.45 | 2.2 ± 0.2 | 1.22 | 0.47 ± 0.01 | 60 ± 1 | 0.62 ± 0.05 | 77.1 | 75.6 | 0.46 | 10.22 | 3.42 | 25.9 |
25.8 | 1.18 ± 0.01 | 0.51 ± 0.01 | 60 ± 1 | 0.36 ± 0.01 | ||||||||
Cy7.5-NEt2-I | 6.45 | 1.55 ± 0.09 | 0.82 | 0.46 ± 0.01 | 59 ± 1 | 0.41 ± 0.03 | 84.7 | 89.4 | 0.99 | 7.22 | 2.82 | 30.8 |
25.8 | 1.02 ± 0.01 | 0.48 ± 0.01 | 57 ± 1 | 0.28 ± 0.02 |
