Table 1 Assignment of the light-induced signals observed in 3-, 4-, and 5-ALA-labelled thylakoid preparations of duckweed (Fig. 6) to carbon positions of either the Chl a donor or the Phe a acceptor cofactor.
Light-induced 13C signal (ppm) | Assignments | Comments | |
|---|---|---|---|
191.0 | E,w | 190 C-13 1 Phe | |
(not observed) | 190.6 C-131 Chl | ||
172.2 | A | 173 C-19 Phe | |
166.8 | A | 170.0 C-19 Chl | |
162.2 | A | 162.0 C-14 Chl | |
160.7 | A | 161 C-16 Phe | |
157.4 | A | 154.0 C-16 Chl | |
156.0 | A | 155.9 C-1 Chl, 156 C-6 Phe | |
154.3 | A | 154.4 C-6 Chl | |
151.8 | A,w | (no match) | |
151.7 | A | 150.7 C-4 Chl, 150 C-9 Phe, 151 C-14 Phe | |
151.6 | A | 147.2 C-11 Chl | |
149.2 | A | 145 C-8 Phe | |
148.5 | A | 150.7 C-4 Chl, 150 C-9 Phe | |
148.3 | A,w | (no match) | |
147.7 | A | 146.2 C-8 Chl | |
146.0 | A | 147.2 C-9 Chl | |
142.5 | E | (no match) | Histidine |
141.0 | A | 142 C-1 Phe | |
139.8 | E | (no match) | Histidine |
138.0 | A,S | 138 C-11 Phe | |
137.4 | A | 138.0 C-3 Chl, 136 C-3 Phe | |
(not observed) | 137 C-4 Phe | ||
136.5 | A,b,w | 136.1 C-2 Chl, 136 C-7 Phe | |
133.7 | A | 133.4 C-7 Chl, 134.0 C-12 Chl | |
(not observed) | 131 C-2 Phe | ||
130.0 | A,S | 133 C-13 Phe | |
129.5 | A | 126.2 C-13 Chl | |
129.2 | E | 128 C-12 Phe | Histidine? |
128.7 | E | 129 C-31 Phe, 128 C-12 Phe | |
125.0 | A,w | 126.2 C-3 1 Chl | |
107.7 | A,w | (no match) | |
106.9 | E | 108.2 C-10 Chl, 107 C-15 Phe | |
104.7 | E | 102.8 C-15 Chl, 105 C-10 Phe | |
97.9 | E | 98.1 C-5 Chl, 97 C-5 Phe | |
92.2 | E | 93.3 C-20 Chl, 93 C-20 Phe | |
51.0 | A | 52 C-17 Phe | (see Fig. 3) |
48.9 | A | 51.4 C-17 Chl | (see Fig. 3) |
29.3 | A,w | 32.5 C-171 Chl, 32 C-171 Phe | (not shown) |
19.6 | A,w | 20.2 C-81 Chl, 20 C-81 Phe | (not shown) |
