Table 4 Dereplication table of the significant and highly correlated putatively active metabolites arranged according to their P-values.
m/z | Rt | Identification/molecular formula | Earlier reported biological source | Reported activity (ref.) | Probability P ≤ 0.05 |
|---|---|---|---|---|---|
1225.5862 [M + H]+ | 15.63 | scillascilloside E2 C57H92O28 | Scilla scilloides | cytotoxic41 | 3.84E-11 |
457.3313 [M − H]− | 15.65 | 3-dehydro-15-deoxoeucosterol C29H44O4 | Scilla scilloides | antiinflammatory44 | 3.33E-11 |
1093.5438 [M + H]+ | 15.63 | mycaloside F deapioplatycodin D C52H84O24 | Mycale laxissima Platycodon grandiflorum | antiviral47 | 1.61E-09 |
1269.5766 [M − H]− | 15.64 | C51H98O35 C58H94O30 | No match | 8.61E-09 | |
1251.6031 [M − H]− | 12.61 | ardisicrenoside C cauloside H C59H96O28 cf. with scillanoside L-2 C59H94O28 | Ardisia crenata Caulophyllum thalictroides Scilla scilloides | 8.43E-08 | |
1267.5977 [M − H]− | 17.15 | soyasaponin A1 C59H96O29 | Impatiens siculifer | antiinflamatory50 | 1.51E-05 |
1283.5914 [M + formate-H]− | 15.73 | zingiberenin G platycoside G2 scillanoside L1 C59H96O30 | Platycodon grandiflorum Dioscorea zingiberensis Scilla scilloides | cytotoxic41 | 4.51E-04 |
1237.5866 [M − H]− | 15.73 | scillanoside L-1 C58H94O28 | Scilla scilloides | cytotoxic41 | 6.27E-04 |
1239.6016 [M+H]+ | 15.74 | scillanoside L-1 C58H94O28 | Scilla scilloides | cytotoxic41 | 5.02E-04 |
563.1411 [M − H]− | 7.35 | flavonoid glycosides anthraquinone glycosides C26H28O14 | widely distributed | cytotoxic51 | 6.47E-04 |
1415.6346 [M − H]− | 15.55 | platycoside G1 C64H104O34 | Platycodon grandiflorum | weak cytotoxic52 | 1.40E-02 |
1369.6269 [M − H]− | 15.56 | heteropappussaponin 7 polygalacin D2 C63H102O32 | Heteropappus altaicus Platycodon grandiflorum | antiproliferative53 | 1.93E-02 |
