Table 2 PDP parameters at various temperatures for MS in 5 M HCl at different concentrations of LHP.
T (°C) | Cinh µmol L−1 | \({\boldsymbol{\beta }}\) a (V decade−1) | \({-{\boldsymbol{\beta }}}_{{\rm{c}}}\) (V decade−1) | Rp Ω cm2 | Ecorr (mV) SCE | icorr (mA cm−2) | IE% | \({\boldsymbol{\theta }}\) |
|---|---|---|---|---|---|---|---|---|
20 | — | 0.14 | 0.19 | 25.1 | 358 | 1.4 | — | — |
92 | 0.1 | 0.162 | 51.6 | 376 | 0.52 | 62 | 0.62 | |
185 | 0.08 | 0.153 | 76.1 | 349 | 0.3 | 78 | 0.78 | |
277 | 0.06 | 0.146 | 97.2 | 380 | 0.19 | 86 | 0.86 | |
370 | 0.03 | 0.131 | 117.7 | 354 | 0.08 | 94 | 0.94 | |
40 | — | 0.21 | 0.261 | 9.7 | 399 | 5.2 | — | — |
92 | 0.184 | 0.241 | 18.8 | 380 | 2.4 | 53 | 0.53 | |
185 | 0.179 | 0.221 | 25.2 | 362 | 1.7 | 67 | 0.67 | |
277 | 0.165 | 0.211 | 34.6 | 358 | 1.16 | 77 | 0.77 | |
370 | 0.153 | 0.209 | 51.8 | 342 | 0.74 | 86 | 0.86 | |
60 | — | 0.23 | 0.298 | 4.8 | 396 | 11.7 | — | — |
92 | 0.188 | 0.285 | 6.9 | 360 | 7.1 | 39 | 0.39 | |
185 | 0.18 | 0.281 | 8.2 | 364 | 5.8 | 50 | 0.5 | |
277 | 0.171 | 0.276 | 10.7 | 354 | 4.3 | 63 | 0.63 | |
370 | 0.165 | 0.269 | 14.3 | 347 | 3.1 | 73 | 0.73 | |
80 | — | 0.242 | 0.302 | 3.4 | 398 | 17.2 | — | — |
92 | 0.197 | 0.32 | 3.8 | 390 | 13.9 | 19 | 0.19 | |
185 | 0.185 | 0.298 | 4.5 | 386 | 11.1 | 35 | 0.35 | |
277 | 0.181 | 0.287 | 5.4 | 382 | 8.9 | 48 | 0.48 | |
370 | 0.173 | 0.278 | 7.1 | 412 | 6.6 | 61 | 0.61 |