Table 1 Physical parameters used in the calculation of melt specific heat and hypercooling limit of BT2.

From: Polymorphic transition and nucleation pathway of barium dititanate (BaTi2O5) during crystallization from undercooled liquid

Property

Symbol [unit]

Value

Atmosphere temperature

T0 [K]

298

Dynamic viscosity of oxygen

η [Pa·S]

3.08 × 10−5 46

Density of oxygen

ρ0 [g L−1]

1.325

Specific heat of oxygen

Cp [J g−1 K−1]

0.91646

Thermal conductivity of oxygen

λ [W m−1K−1]

0.039946

Radius of sphere

R [m]

0.000889

Density of sphere

ρs [g mL−1]

3.945

Emissivity

ε

0.947

Stefan–Boltzmann constant

σ [W m−2 K−4]

5.67 × 10−8

Mean speed of Oxygen surrounding sample

υ [m s−1]

15.82

Reynolds number

Re

1180

Planck number

Pr

0.7057

Heat-transfer coefficient

h [W m−2 K−1]

283.8

Specific heat of BT2 melt

CpL [J mol−1 K−1]

206.2(3) ± 4.2(9)

Heat of fusion

ΔHf [KJ mol−1]

81.4