Table 2 Most probable phases from the structural viewpoint identified by selected electron diffraction investigations (SAED), their theoretical and experimentally measured stoichiometry (normalized to B) and the theoretical and experimental Al/C ratio.
Sample | Phase | Normalized phase to B | Phase Ratio Al/C | Experimental EDS stoichiometry (Normalized to B) | Experimental EDS ratio (Al/C) | SAED representative image is presented in: |
|---|---|---|---|---|---|---|
‘21’ | AlB31 | Al0.031B | — | Al0.023–0.047BC0.016–0.018 | 1.44–2.61 | Fig. 6 area 1 |
AlB24C4 | Al0.042BC0.167 | 0.25 | Al0.011–0.0175BC0.058–0.097 | 0.19–0.18 | Fig. 6 area 2 | |
‘31’ | Al0.3B13C1.3 | Al0.023BC0.1 | 0.23 | Al0.02BC0.097 | 0.21 | Fig. 7(a) area 1 |
Al rich | — | — | Al0.126–0.224BC0.094–0.11 | 1.34–2.04 | Fig. 7(b) area 1 |