Table 1 The activation energies (Ea) for the transition processes from the L- to M-intermediate (L → M), from the M- to O-intermediate (M → O), and from the O-intermediate to original state (O → original) of RxR and those of BR. The Ea values for BR were subtracted from those for RxR to obtain ΔEa. The percentages of ΔEa to Ea for RxR were shown in brackets.
Ea for RxR | Ea for BR | ΔEa | |
|---|---|---|---|
L → M | 63.4 kJ/mol | 47 kJ/mol13 | 16.4 kJ/mol (26%) |
M → O | 58.7 kJ/mol | 47 kJ/mol13 | 11.7 kJ/mol (20%) |
O → original | 45.8 kJ/mol | 36 kJ/mol13 | 9.8 kJ/mol (21%) |