Figure 2

The 800 MHz 2D DOSY spectra of the HWE tea samples. Overlay of the (a) unburied tea spectra with RMI/RMII and (b) grassland/woodland spectra. Selected areas are labelled and discussed in the text. Blue stars above the spectra indicate signals of amylopectin, arabinogalactans are labelled by horizontal bars, dashed bars indicate signals of trehalose and mannitol. Orange stars indicate OCH3 groups. Question marks label unassigned signals from large molecules. Catechin signals are marked by purple bars. The shift of the signals towards larger molecular weight seen in the grassland spectra could be due to presence of oxidation products of catechins, e.g. Theasinensins42.