Table 3 Summary of ligand field calculations.

From: Structure and mechanism of potent bifunctional β-lactam- and homoserine lactone-degrading enzymes from marine microorganisms

 

Origin in Oh

d–d transition (nm)

Observed

Calculated

MIM-1

\({}^{4}{T}_{1g}\to {}{}^{2}{T}_{1g}(G)\)

463

469

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

490

487

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

507

503

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

520

512

\({}^{4}{T}_{1g}\to {}{}^{4}{A}_{2g}\)

565

559

SAM-1

\({}^{4}{T}_{1g}\to {}{}^{2}{T}_{1g}(G)\)

470

465

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

490

490

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

505

506

\({}^{4}{T}_{1g}\to {}{}^{4}{T}_{1g}(P)\)

517

518

\({}^{4}{T}_{1g}\to {}{}^{4}{A}_{2g}\)

567

566

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