Table 3 Ash yield (%, db), major and minor (wt %, db), and trace elements (μg/g, db) concentrations in the coals from the Fengfeng–Handan Coalfield (Dai and Ren, 200710) and related ratios.
Element | No. 1 | No. 2 | No. 3 | No. 4 | No. 5 | No. 6 | No. 7 | No. 8 | No. 9 | No. 10 | No. 11 | No. 12 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
Ash yield | 18.5 | 16.2 | 19.5 | 16.1 | 18.6 | 20.6 | 22.4 | 19.7 | 23.4 | 26.6 | 30.3 | 22.1 |
Al2O3 | 6.49 | 5.24 | 7.21 | 5.53 | 6.85 | 6.86 | 7.21 | 12.57 | 6.93 | 8.22 | 5.48 | 5.47 |
SiO2 | 13.25 | 11.85 | 15.86 | 11.25 | 13.54 | 15.47 | 14.86 | 21.22 | 15.25 | 18.45 | 14.06 | 12.05 |
MgO | 0.26 | 0.15 | 0.13 | 0.44 | 0.28 | 0.44 | 0.68 | 1.52 | 1.22 | 0.98 | 1.38 | 1.41 |
CaO | 0.89 | 0.78 | 1.65 | 0.68 | 1.81 | 0.48 | 1.21 | 10.36 | 4.25 | 1.92 | 6.65 | 8.54 |
K2O | 0.27 | 0.28 | 0.05 | 0.46 | 0.05 | 0.26 | 0.18 | 0.10 | 0.18 | 0.28 | 0.05 | 0.25 |
Na2O | 0.09 | 0.11 | 0.43 | 0.19 | 0.16 | 0.08 | 0.09 | 0.07 | 0.10 | 0.05 | 0.23 | 0.35 |
TiO2 | 0.34 | 0.24 | 0.14 | 0.52 | 0.59 | 0.49 | 0.32 | 0.78 | 0.33 | 0.22 | 0.70 | 0.68 |
Fe2O3 | 0.60 | 0.65 | 0.78 | 0.54 | 0.72 | 0.89 | 0.84 | 1.25 | 1.84 | 2.65 | 8.56 | 1.48 |
MnO2 | 0.09 | 0.03 | 0.02 | 0.02 | 0.01 | 0.10 | 0.06 | 0.17 | 0.15 | 0.10 | 0.17 | 0.20 |
P2O5 | 0.03 | 0.03 | 0.03 | 0.41 | 0.02 | 0.02 | 0.51 | 0.83 | 0.16 | 0.22 | 0.76 | 0.49 |
Al | 3.435 | 2.774 | 3.816 | 2.927 | 3.626 | 3.631 | 3.816 | 6.6545 | 3.668 | 4.3516 | 2.9011 | 2.8958 |
Si | 6.188 | 5.534 | 7.407 | 5.254 | 6.323 | 7.224 | 6.94 | 9.91 | 7.122 | 8.616 | 6.566 | 5.627 |
Mg | 0.157 | 0.09 | 0.078 | 0.265 | 0.169 | 0.265 | 0.41 | 0.917 | 0.736 | 0.591 | 0.832 | 0.85 |
Ca | 0.636 | 0.558 | 1.18 | 0.486 | 1.294 | 0.343 | 0.865 | 7.407 | 3.039 | 1.373 | 4.755 | 6.106 |
K | 0.224 | 0.232 | 0.042 | 0.382 | 0.042 | 0.216 | 0.149 | 0.083 | 0.149 | 0.232 | 0.042 | 0.208 |
Na | 0.067 | 0.082 | 0.319 | 0.141 | 0.119 | 0.059 | 0.067 | 0.052 | 0.074 | 0.037 | 0.171 | 0.26 |
Ti | 0.204 | 0.144 | 0.084 | 0.311 | 0.353 | 0.294 | 0.192 | 0.467 | 0.198 | 0.132 | 0.419 | 0.407 |
Mn | 0.057 | 0.019 | 0.013 | 0.013 | 0.006 | 0.063 | 0.038 | 0.107 | 0.095 | 0.063 | 0.107 | 0.126 |
Fe | 0.419 | 0.454 | 0.545 | 0.377 | 0.503 | 0.622 | 0.587 | 0.874 | 1.286 | 1.852 | 5.983 | 1.035 |
P | 0.013 | 0.013 | 0.013 | 0.179 | 0.009 | 0.009 | 0.222 | 0.362 | 0.07 | 0.096 | 0.331 | 0.214 |
As | 2.31 | 1.25 | 0.55 | 3.51 | 1.59 | 0.79 | 2.46 | 12.88 | 7.45 | 42.23 | 48.41 | 18.38 |
Ba | 145.2 | 131.3 | 123.6 | 178.5 | 192.5 | 144.3 | 184.7 | 178.4 | 254.6 | 115.8 | 89.4 | 150.3 |
B | 24.5 | 27.8 | 32.4 | 29.8 | 32.4 | 28.7 | 27.6 | 26.9 | 61.5 | 66.9 | 78.6 | 57.5 |
Be | 2.11 | 1.67 | 1.22 | 2.34 | 2.55 | 2.57 | 1.74 | 0.65 | 1.80 | 0.88 | 1.52 | 2.20 |
Bi | 0.29 | 0.18 | 0.13 | 0.43 | 1.04 | 0.24 | 0.49 | 0.99 | 0.17 | 0.45 | 0.20 | 0.41 |
Br | 9.85 | 10.54 | 11.50 | 10.70 | 6.80 | 12.50 | 15.80 | 95.40 | 73.20 | 112.80 | 98.50 | 70.60 |
Ce | 33.11 | 33.08 | 23.63 | 30.60 | 26.65 | 32.35 | 29.83 | 43.54 | 26.88 | 34.37 | 39.14 | 26.81 |
Cl | 96.9 | 100.7 | 114.5 | 87.6 | 124.4 | 214.9 | 563.2 | 756.3 | 869.7 | 1,220.0 | 720.4 | 685.5 |
Co | 2.80 | 2.45 | 2.30 | 1.50 | 1.00 | 3.50 | 2.80 | 4.20 | 14.60 | 29.20 | 33.70 | 18.90 |
Cr | 18.40 | 10.55 | 19.10 | 9.60 | 15.80 | 18.70 | 21.50 | 10.50 | 14.70 | 13.30 | 19.10 | 15.40 |
Cs | 0.12 | 0.22 | 0.85 | 0.14 | 0.91 | 0.54 | 0.25 | 0.11 | 0.09 | 0.04 | 0.18 | 0.09 |
Cu | 8.54 | 11.58 | 26.50 | 15.40 | 9.87 | 14.60 | 14.70 | 11.20 | 65.40 | 121.50 | 181.40 | 90.80 |
Dy | 2.48 | 2.45 | 1.52 | 2.75 | 1.51 | 1.80 | 1.87 | 2.27 | 2.28 | 1.61 | 2.73 | 1.42 |
Er | 1.36 | 1.33 | 0.86 | 1.60 | 0.88 | 1.12 | 1.07 | 1.30 | 1.42 | 0.93 | 1.57 | 0.84 |
Eu | 0.69 | 0.64 | 0.38 | 0.62 | 0.38 | 0.54 | 0.51 | 0.55 | 0.50 | 0.46 | 0.57 | 0.36 |
F | 85.9 | 90.7 | 98.5 | 86.4 | 62.2 | 78.2 | 101.4 | 125.2 | 652.8 | 423.5 | 1,212.1 | 885.6 |
Ga | 12.50 | 13.46 | 14.80 | 5.64 | 8.37 | 9.81 | 11.50 | 12.78 | 15.44 | 3.50 | 9.80 | 8.34 |
Gd | 2.70 | 2.67 | 1.63 | 2.86 | 1.68 | 2.04 | 2.05 | 2.56 | 2.45 | 1.95 | 2.86 | 1.74 |
Hf | 1.56 | 1.52 | 1.23 | 0.88 | 1.56 | 1.08 | 2.24 | 1.30 | 0.86 | 1.11 | 1.21 | 0.98 |
Hg | 0.14 | 0.08 | 0.09 | 0.12 | 0.05 | 0.09 | 0.07 | 0.09 | 0.55 | 0.59 | 1.64 | 1.32 |
Ho | 0.50 | 0.47 | 0.31 | 0.55 | 0.31 | 0.38 | 0.37 | 0.45 | 0.48 | 0.33 | 0.53 | 0.30 |
La | 17.23 | 17.20 | 12.98 | 15.52 | 14.55 | 17.89 | 15.96 | 24.37 | 13.58 | 20.68 | 19.09 | 13.88 |
Lu | 0.20 | 0.18 | 0.15 | 0.25 | 0.14 | 0.20 | 0.18 | 0.20 | 0.24 | 0.15 | 0.24 | 0.15 |
Mo | 3.41 | 2.89 | 3.50 | 1.36 | 4.30 | 2.20 | 2.42 | 2.90 | 2.88 | 2.41 | 2.11 | 1.25 |
Nb | 18.54 | 18.51 | 17.65 | 5.98 | 12.65 | 8.74 | 14.56 | 10.25 | 9.62 | 15.89 | 14.75 | 20.34 |
Nd | 14.12 | 14.09 | 9.43 | 13.90 | 9.99 | 12.19 | 11.83 | 14.66 | 11.88 | 11.04 | 14.87 | 10.51 |
Ni | 3.15 | 2.78 | 1.40 | 2.32 | 7.75 | 5.40 | 6.63 | 21.66 | 20.77 | 56.89 | 74.59 | 28.65 |
Pb | 25.64 | 22.12 | 21.53 | 8.59 | 21.28 | 15.96 | 13.51 | 18.29 | 25.44 | 70.24 | 86.58 | 57.85 |
Pr | 3.77 | 3.74 | 2.59 | 3.64 | 2.79 | 3.42 | 3.29 | 4.36 | 3.04 | 3.29 | 4.20 | 2.84 |
Rb | 1.54 | 1.51 | 1.89 | 1.11 | 1.04 | 1.28 | 2.15 | 1.54 | 2.66 | 24.50 | 18.90 | 8.08 |
Sb | 6.42 | 6.33 | 8.95 | 5.48 | 3.55 | 2.54 | 3.60 | 1.11 | 0.18 | 0.76 | 0.89 | 0.47 |
Sc | 5.58 | 5.21 | 5.22 | 6.45 | 6.32 | 6.85 | 3.21 | 3.96 | 3.47 | 4.14 | 3.12 | 4.15 |
Se | 3.58 | 3.44 | 2.12 | 1.25 | 2.56 | 2.76 | 1.91 | 1.93 | 1.05 | 0.94 | 11.85 | 0.68 |
Sm | 2.82 | 2.79 | 1.71 | 2.94 | 1.75 | 2.13 | 2.15 | 2.59 | 2.35 | 1.83 | 2.97 | 1.74 |
Sn | 7.85 | 8.95 | 11.23 | 8.45 | 10.68 | 12.04 | 8.37 | 11.21 | 6.34 | 8.67 | 13.09 | 6.52 |
Sr | 187.5 | 100.5 | 199.3 | 168.0 | 288.4 | 197.1 | 236.1 | 220.5 | 589.5 | 1,024.5 | 1732.4 | 2,422.0 |
Ta | 0.32 | 0.28 | 0.26 | 0.15 | 0.83 | 0.54 | 0.15 | 0.32 | 0.11 | 0.20 | 0.52 | 0.23 |
Tb | 0.41 | 0.38 | 0.26 | 0.47 | 0.26 | 0.31 | 0.32 | 0.39 | 0.40 | 0.28 | 0.44 | 0.25 |
Th | 9.70 | 10.20 | 11.66 | 3.65 | 10.25 | 18.40 | 3.42 | 10.07 | 3.10 | 8.66 | 6.70 | 6.71 |
Tm | 0.20 | 0.17 | 0.14 | 0.24 | 0.14 | 0.17 | 0.16 | 0.19 | 0.21 | 0.14 | 0.24 | 0.13 |
U | 1.54 | 1.25 | 0.75 | 1.21 | 1.25 | 2.38 | 1.85 | 8.50 | 25.51 | 32.48 | 24.32 | 21.59 |
V | 55.56 | 54.88 | 93.65 | 52.87 | 65.82 | 54.09 | 20.75 | 28.54 | 18.49 | 16.58 | 15.44 | 22.36 |
W | 1.57 | 1.04 | 1.94 | 0.89 | 1.15 | 2.22 | 0.59 | 1.76 | 2.40 | 2.36 | 2.41 | 2.54 |
Y | 12.53 | 12.48 | 14.34 | 9.96 | 12.66 | 11.22 | 7.85 | 7.40 | 8.00 | 5.66 | 15.27 | 6.89 |
Yb | 1.22 | 1.19 | 0.83 | 1.55 | 0.82 | 1.08 | 1.03 | 1.18 | 1.39 | 0.82 | 1.55 | 0.80 |
Zn | 25.63 | 32.62 | 35.21 | 45.71 | 35.42 | 17.89 | 34.57 | 138.20 | 88.45 | 70.62 | 121.40 | 150.50 |
Zr | 305.8 | 251.6 | 154.8 | 265.4 | 302.5 | 127.2 | 170.0 | 75.4 | 105.8 | 92.8 | 131.0 | 112.4 |
Th/U | 6.298 | 8.16 | 15.54 | 3.016 | 8.2 | 7.731 | 1.848 | 1.1847 | 0.121 | 0.2666 | 0.2754 | 0.3107 |
Sr/Ba | 1.291 | 0.765 | 1.612 | 0.941 | 1.498 | 1.365 | 1.278 | 12.359 | 2.315 | 8.8471 | 19.378 | 16.114 |
Th/Co | 3.464 | 4.163 | 5.069 | 2.433 | 10.25 | 5.257 | 1.221 | 2.3976 | 0.212 | 0.2965 | 0.1988 | 0.3550 |
Zr/Hf | 196.0 | 165.5 | 125.8 | 301.5 | 193.9 | 117.7 | 75.89 | 58 | 123.0 | 83.603 | 108.26 | 114.69 |
Zr/Nb | 16.49 | 13.59 | 8.770 | 44.38 | 23.91 | 14.55 | 11.67 | 7.3560 | 10.99 | 5.8401 | 8.8813 | 5.5260 |
Yb/La | 0.070 | 0.069 | 0.063 | 0.099 | 0.056 | 0.060 | 0.064 | 0.0484 | 0.102 | 0.0396 | 0.0811 | 0.0576 |
Nb/Ta | 57.93 | 66.10 | 67.88 | 39.86 | 15.24 | 16.18 | 97.06 | 32.031 | 87.45 | 79.45 | 28.365 | 88.434 |
(SiO + Al2O3)/(Fe2O3 + CaO + MgO) | 11.28 | 10.81 | 9.012 | 10.10 | 7.256 | 12.34 | 8.084 | 2.573 | 3.034 | 4.805 | 1.1779 | 1.5328 |