Table 1 The estimated theoretical parameters of the kinetic models, isotherm models, and the thermodynamic studies.
Kinetic models | Isotherm models | ||||
|---|---|---|---|---|---|
Model | Parameters | LVX | Model | Parameters | LVX |
Pseudo-first order | k1 (mg/min) | 0.006 | Langmuir | qmax (mg/g) | 106.75 |
b(L/mg) | 0.219 | ||||
qe (Cal) (mg/g) | 37.73 | R2 | 0.98 | ||
R2 | 0.98 | RL | 0.044–0.313 | ||
X2 | 0.16 | ||||
Pseudo-Second order | k2 (mg/min) | 1.86 × 10–4 | Freundlich | 1/n | 0.249 |
KF | 40.31 | ||||
R2 | 0.83 | ||||
qe (Cal) (mg/g) | 48.78 | X2 | 0.321 | ||
R2 | 0.99 | ||||
Elovich | β (g/mg) | 0.0976 | Dubinin–Radushkevich | β (mol2/KJ2) | 12.35 |
qm (mg/g) | 99.14 | ||||
α (mg/g min) | 108.65 | R2 | 0.90 | ||
E (KJ/mol) | 0.2 | ||||
R2 | 0.96 | ||||
Parameters | Thermodynamic parameters | ||||
|---|---|---|---|---|---|
Temperature (K) | LVX | ||||
∆G° (kJ mol−1) | 303 | − 19.54 | |||
308 | − 19.64 | ||||
313 | − 19.42 | ||||
318 | − 18.95 | ||||
323 | − 18.12 | ||||
328 | − 17.01 | ||||
333 | − 14.24 | ||||
ΔH° (kJ mol−1) | − 67.78 | ||||
ΔS° (J K−1 mol−1) | − 156.15 | ||||