Table 1 Data for the ethylene oligomerization catalyzed by chromium(III)-based complexes.
From: New chromium(III)-based catalysts for ethylene oligomerization
Compound | Oligomerization process time (h) | Catalytic activity (g∙mmol-1∙h-1 ∙bar-1) | Gas pressure (bar) |
|---|---|---|---|
[Cr(dipic)2][Cr(bipy)(dipic)(H2O)] ∙ 2 H2O | 1/3 | 2459 | 0.3 |
[Cr(dipic)2]Hdmbipy ∙ 2.5 H2O | 1/3 | 3798 | 0.2 |
cis-K[Cr(C2O4)(OH2)2] | 1/6 | 1860 | 0.2 |
[Cr(dipic)(H2O)3]Cl ∙ 2 H2O | 1/6 | 2064 | 0.2 |
3 (C18H15CrN6O6) ∙ CHCl3 ∙ 5 H2O | 1/6 | 2703 | 0.2 |
