Table 14 Coefficients of Ai’s in Eq. (10) for the binary solutions of KCl + H2O and CaCl2 + H2O.
T/ K | 293.15 | 298.15 | 303.15 | 308.15 | 313.15 | 318.15 | 323.15 |
|---|---|---|---|---|---|---|---|
KCl + H2O | |||||||
A0 (mPa s) | 1.001 | 0.891 | 0.798 | 0.720 | 0.661 | 0.653 | 0.540 |
102A1 (mPa s kg1/2 mol−1/2) | 1.31 | − 0.092 | − 0.062 | 0.117 | − 0.177 | − 0.141 | 2.25 |
104A2 (mPa s kg1 mol−1) | − 490 | 0.988 | 1.01 | 0.83 | 0.78 | 0.79 | 1.04 |
102A3 (mPa s kg3/2 mol−3/2) | 2.48 | − 2.00 | 1.17 | 1.86 | − 1.72 | 2.24 | − 0.18 |
103A4 (mPa s kg2 mol−2) | − 1.09 | 20.7 | − 5.75 | − 23.7 | 44.0 | − 10.2 | 8.00 |
103A5 (mPa s kg5/2 mol−5/2) | 0.49 | − 3.82 | 1.84 | 15.80 | 2.35 | 2.07 | − 1.50 |
105A6 (mPa s kg 3 mol−3) | 7.00 | − 0.0063 | 4.980 | − 324.00 | 415 | 4.48 | − 16.3 |
CaCl2 + H2O | |||||||
A0 (mPa s) | 1.207 | 1.085 | 0.9745 | 0.718 | 0.742 | 0.535 | 0.553 |
102A1 (mPa s kg1/2 mol−1/2) | − 0.219 | − 0.387 | 0.0797 | 0.0635 | − 0.1268 | 0.2683 | 0.0297 |
104A2 (mPa s kg1 mol−1) | − 0.859 | − 0.213 | 0.0002 | − 0.0253 | − 0.198 | 0.0735 | 0.0037 |
102A3 (mPa s kg3/2 mol−3/2) | 2.345 | 1.541 | 0.0065 | 0.430 | 0.966 | − 0.908 | 0.3205 |
103A4 (mPa s kg2 mol−2) | − 1.471 | − 1.1162 | 0.0404 | − 0.3143 | − 0.666 | 1.603 | − 0.171 |
103A5 (mPa s kg5/2 mol−5/2) | 0.289 | 0.264 | − 0.0268 | 0.1034 | 0.1612 | − 0.948 | 0.0175 |
105A6 (mPa s kg 3 mol−3) | 0.0280 | 0.0132 | 0.0047 | 0.0039 | 0.0072 | 0.2004 | 0.0167 |