Table 7 Experimental and calculated densities \(\rho\) and viscosities \(\eta\) at T = 313.15 K for KCl (1) + CaCl2 (2) + H2O (3) system.
m1 (mol kg−1) | Experimental data | Calculated viscosity (mPa s) | Predicted density | ||
|---|---|---|---|---|---|
\(\rho\) (g cm−3) | \(\eta\) (mPa s) | Equation (5) | Hu’s model | \(\rho\) (g cm−3) | |
m2 = 0.5 | |||||
0.5 | 1.0561 | 0.7879 | 0.7713 | 0.7675 | 1.0561 |
1.0 | 1.0756 | 0.7920 | 0.7836 | 0.7793 | 1.0757 |
1.5 | 1.0950 | 0.8051 | 0.7966 | 0.7922 | 1.0945 |
2.0 | 1.1132 | 0.8145 | 0.8102 | 0.8059 | 1.1124 |
2.5 | 1.1347 | 0.8270 | 0.8248 | 0.8206 | 1.1296 |
3.0 | 1.1474 | 0.8396 | 0.8412 | 0.8372 | 1.1461 |
3.5 | 1.1634 | 0.8634 | 0.8576 | 0.8540 | 1.1617 |
m2 = 1.0 | |||||
0.5 | 1.0953 | 0.9059 | 0.8970 | 0.8997 | 1.0947 |
1.0 | 1.1125 | 0.9108 | 0.9137 | 0.9148 | 1.1128 |
1.5 | 1.1322 | 0.9237 | 0.9306 | 0.9306 | 1.1300 |
2.0 | 1.1486 | 0.9410 | 0.9501 | 0.9497 | 1.1467 |
2.5 | 1.1652 | 0.9698 | 0.9675 | 0.9672 | 1.1620 |
3.0 | 1.1808 | 0.9797 | 0.9876 | 0.9883 | 1.1769 |
m2 = 1.5 | |||||
0.5 | 1.1321 | 1.0509 | 1.0458 | 1.0513 | 1.1305 |
1.0 | 1.1492 | 1.0659 | 1.0669 | 1.0707 | 1.1471 |
1.5 | 1.1663 | 1.0809 | 1.0879 | 1.0914 | 1.1627 |
2.0 | 1.1823 | 1.1011 | 1.1105 | 1.1154 | 1.1777 |
2.5 | 1.1978 | 1.1173 | 1.1338 | 1.1417 | 1.1917 |
m2 = 2.0 | |||||
0.5 | 1.1681 | 1.2273 | 1.2245 | 1.2279 | 1.1643 |
1.0 | 1.1839 | 1.2598 | 1.2497 | 1.2547 | 1.1793 |
1.5 | 1.1995 | 1.2684 | 1.2752 | 1.2844 | 1.1934 |
2.0 | 1.2148 | 1.2979 | 1.3041 | 1.3201 | 1.2069 |
m2 = 2.5 | |||||
0.5 | 1.2019 | 1.4444 | 1.4400 | 1.4417 | 1.1963 |
1.0 | 1.2170 | 1.4731 | 1.4693 | 1.4800 | 1.2097 |
1.5 | 1.2320 | 1.4963 | 1.4995 | 1.5227 | 1.2222 |
m2 = 3.0 | |||||
0.5 | 1.2337 | 1.7043 | 1.7032 | 1.7100 | 1.2271 |
1.0 | 1.2481 | 1.7345 | 1.7363 | 1.7635 | 1.2387 |
m2 = 3.5 | |||||
0.5 | 1.2633 | 2.0334 | 2.0254 | 2.0485 | 1.2569 |
1.0 | 1.2777 | 2.0810 | 2.0634 | 2.1225 | 1.2668 |
m2 = 4.0 | |||||
0.5 | 1.2925 | 2.4705 | 2.4250 | 2.4753 | 1.2861 |
AAD% = 0.78 | AAD% = 1.04 | AAD% = 0.34 | |||
SD = 0.0127 | SD = 0.0154 | SD = 0.0047 | |||