Table 7 Experimental and calculated densities \(\rho\) and viscosities \(\eta\) at T = 313.15 K for KCl (1) + CaCl2 (2) + H2O (3) system.

From: Experimental measurements and modelling of viscosity and density of calcium and potassium chlorides ternary solutions

m1 (mol kg−1)

Experimental data

Calculated viscosity (mPa s)

Predicted density

\(\rho\) (g cm−3)

\(\eta\) (mPa s)

Equation (5)

Hu’s model

\(\rho\) (g cm−3)

   

m2 = 0.5

  

0.5

1.0561

0.7879

0.7713

0.7675

1.0561

1.0

1.0756

0.7920

0.7836

0.7793

1.0757

1.5

1.0950

0.8051

0.7966

0.7922

1.0945

2.0

1.1132

0.8145

0.8102

0.8059

1.1124

2.5

1.1347

0.8270

0.8248

0.8206

1.1296

3.0

1.1474

0.8396

0.8412

0.8372

1.1461

3.5

1.1634

0.8634

0.8576

0.8540

1.1617

   

m2 = 1.0

  

0.5

1.0953

0.9059

0.8970

0.8997

1.0947

1.0

1.1125

0.9108

0.9137

0.9148

1.1128

1.5

1.1322

0.9237

0.9306

0.9306

1.1300

2.0

1.1486

0.9410

0.9501

0.9497

1.1467

2.5

1.1652

0.9698

0.9675

0.9672

1.1620

3.0

1.1808

0.9797

0.9876

0.9883

1.1769

   

m2 = 1.5

  

0.5

1.1321

1.0509

1.0458

1.0513

1.1305

1.0

1.1492

1.0659

1.0669

1.0707

1.1471

1.5

1.1663

1.0809

1.0879

1.0914

1.1627

2.0

1.1823

1.1011

1.1105

1.1154

1.1777

2.5

1.1978

1.1173

1.1338

1.1417

1.1917

   

m2 = 2.0

  

0.5

1.1681

1.2273

1.2245

1.2279

1.1643

1.0

1.1839

1.2598

1.2497

1.2547

1.1793

1.5

1.1995

1.2684

1.2752

1.2844

1.1934

2.0

1.2148

1.2979

1.3041

1.3201

1.2069

   

m2 = 2.5

  

0.5

1.2019

1.4444

1.4400

1.4417

1.1963

1.0

1.2170

1.4731

1.4693

1.4800

1.2097

1.5

1.2320

1.4963

1.4995

1.5227

1.2222

   

m2 = 3.0

  

0.5

1.2337

1.7043

1.7032

1.7100

1.2271

1.0

1.2481

1.7345

1.7363

1.7635

1.2387

   

m2 = 3.5

  

0.5

1.2633

2.0334

2.0254

2.0485

1.2569

1.0

1.2777

2.0810

2.0634

2.1225

1.2668

   

m2 = 4.0

  

0.5

1.2925

2.4705

2.4250

2.4753

1.2861

   

AAD% = 0.78

AAD% = 1.04

AAD% = 0.34

   

SD = 0.0127

SD = 0.0154

SD = 0.0047

  1. The standard uncertainties (u) are u(T) = 0.02 K, u(m) = 1.0 × 10−4 mol kg−1. The combined expanded uncertainty (Uc) are Uc(ρ) = 5.0 × 10−5 g cm−3 (0.95 level of confidence) and Uc(\(\eta\)) = 0.003 mPa s (0.95 level of confidence).