Table 8 Experimental and calculated densities \(\rho\) and Viscosities \(\eta\) at T = 318.15 K for KCl (1) + CaCl2 (2) + H2O (3) SYSTEM.

From: Experimental measurements and modelling of viscosity and density of calcium and potassium chlorides ternary solutions

m1 (mol kg−1)

Experimental data

Calculated viscosity (mPa s)

Predicted density

\(\rho\) (g cm−3)

\(\eta\) (mPa s)

Equation (5)

Hu’s model

\(\rho\) (g cm−3)

   

m2 = 0.5

  

0.5

1.0539

0.7214

0.7087

0.7140

1.0566

1.0

1.0735

0.7345

0.7207

0.7272

1.0764

1.5

1.0923

0.7434

0.7331

0.7408

1.0950

2.0

1.1101

0.7537

0.7458

0.7547

1.1128

2.5

1.1272

0.7656

0.7591

0.7691

1.1299

3.0

1.1435

0.7851

0.7739

0.7846

1.1465

3.5

1.1588

0.8057

0.7887

0.7994

1.1626

   

m2 = 1.0

  

0.5

1.0925

0.8341

0.8258

0.8474

1.0955

1.0

1.1105

0.8404

0.8405

0.8612

1.1133

1.5

1.1276

0.8566

0.8552

0.8751

1.1305

2.0

1.1441

0.8865

0.8720

0.8911

1.1477

2.5

1.1592

0.8970

0.8866

0.9045

1.1639

3.0

1.1737

0.9077

0.9035

0.9197

1.1802

   

m2 = 1.5

  

0.5

1.1283

0.9716

0.9647

0.9895

1.1307

1.0

1.1447

0.9840

0.9822

1.0043

1.1480

1.5

1.1600

0.9917

0.9993

1.0190

1.1649

2.0

1.1746

1.0251

1.0176

1.0347

1.1818

2.5

1.1883

1.0496

1.0363

1.0504

1.1987

   

m2 = 2.0

  

0.5

1.1619

1.1300

1.1319

1.1481

1.1653

1.0

1.1765

1.1653

1.1518

1.1649

1.1827

1.5

1.1902

1.1680

1.1717

1.1818

1.2000

2.0

1.2032

1.1964

1.1945

1.2009

1.2180

   

m2 = 2.5

  

0.5

1.1935

1.3299

1.3340

1.3374

1.1998

1.0

1.2064

1.3538

1.3563

1.3571

1.2180

1.5

1.2183

1.3826

1.3792

1.3767

1.2365

   

m2 = 3.0

  

0.5

1.2237

1.5666

1.5818

1.5763

1.2344

1.0

1.2347

1.6321

1.6063

1.5984

1.2538

   

m2 = 3.5

  

0.5

1.2528

1.8659

1.8879

1.8827

1.2682

1.0

1.2619

1.9129

1.9156

1.9053

1.2894

   

m2 = 4.0

  

0.5

1.2812

2.2479

2.2726

2.2750

1.3005

   

AAD% = 0.90

AAD% = 0.99

AAD% = 0.39

   

SD = 0.0130

SD = 0.0138

SD = 0.0054

  1. The standard uncertainties (u) are u(T) = 0.02 K, u(m) = 1.0 × 10−4 mol kg−1. The combined expanded uncertainty (Uc) are Uc(ρ) = 5.0 × 10−5 g cm−3 (0.95 level of confidence) and Uc(\(\eta\)) = 0.003 mPa s (0.95 level of confidence).