Table 9 Experimental and calculated densities \(\rho\) and viscosities \(\eta\) at T = 323.15 K for KCl (1) + CaCl2 (2) + H2O (3) system.

From: Experimental measurements and modelling of viscosity and density of calcium and potassium chlorides ternary solutions

m1 (mol kg−1)

Experimental data

Calculated viscosity (mPa s)

Predicted density

\(\rho\) (g cm−3)

\(\eta\) (mPa s)

Equation (5)

Hu’s model

\(\rho\) (g cm−3)

   

m2 = 0.5

  

0.5

1.0507

0.6662

0.6551

0.6633

1.0542

1.0

1.0714

0.6771

0.6689

0.6754

1.0756

1.5

1.0902

0.6892

0.6828

0.6881

1.0956

2.0

1.1083

0.7004

0.6970

0.7010

1.1146

2.5

1.1297

0.7134

0.7116

0.7140

1.1324

3.0

1.1424

0.7284

0.7274

0.7275

1.1494

4.0

1.1583

0.7544

0.7430

0.7396

1.1653

   

m2 = 1.0

  

0.5

1.0907

0.7685

0.7648

0.7836

1.0917

1.0

1.1088

0.7825

0.7819

0.7968

1.1110

1.5

1.1273

0.7950

0.7989

0.8097

1.1290

2.0

1.1436

0.8099

0.8178

0.8238

1.1464

2.5

1.1601

0.8272

0.8344

0.8347

1.1622

3.0

1.1756

0.8434

0.8530

0.8462

1.1773

   

m2 = 1.5

  

0.5

1.1271

0.8906

0.8931

0.9176

1.1271

1.0

1.1445

0.9092

0.9138

0.9310

1.1444

1.5

1.1613

0.9217

0.9338

0.9430

1.1605

2.0

1.1772

0.9518

0.9550

0.9546

1.1758

2.5

1.1926

0.9603

0.9764

0.9646

1.1900

   

m2 = 2.0

  

0.5

1.1416

1.0246

1.0452

1.0715

1.1604

1.0

1.1788

1.0783

1.0690

1.0835

1.1758

1.5

1.1943

1.0826

1.0927

1.0934

1.1900

2.0

1.2095

1.1095

1.1188

1.1032

1.2035

   

m2 = 2.5

  

0.5

1.1968

1.2266

1.2261

1.2531

1.1920

1.0

1.2117

1.2549

1.2530

1.2611

1.2054

1.5

1.2267

1.2846

1.2803

1.2657

1.2178

   

m2 = 3.0

  

0.5

1.2283

1.4415

1.4437

1.4718

1.2223

1.0

1.2427

1.4802

1.4735

1.4699

1.2337

   

m2 = 3.5

  

0.5

1.2578

1.7161

1.7070

1.7327

1.2516

1.0

1.2720

1.7557

1.7407

1.7092

1.2609

   

m2 = 4.0

  

0.5

1.2868

2.0785

2.0306

2.0326

1.2802

   

AAD% = 0.79

AAD% = 1.31

AAD% = 0.40

   

SD = 0.0124

SD = 0.0199

SD = 0.0056

  1. The standard uncertainties (u) are u(T) = 0.02 K, u(m) = 1.0 × 10−4 mol kg−1. The combined expanded uncertainty (Uc) are Uc(ρ) = 5.0 × 10−5 g cm−3 (0.95 level of confidence) and Uc(\(\eta\)) = 0.003 mPa s (0.95 level of confidence).