Table 9 Experimental and calculated densities \(\rho\) and viscosities \(\eta\) at T = 323.15 K for KCl (1) + CaCl2 (2) + H2O (3) system.
m1 (mol kg−1) | Experimental data | Calculated viscosity (mPa s) | Predicted density | ||
|---|---|---|---|---|---|
\(\rho\) (g cm−3) | \(\eta\) (mPa s) | Equation (5) | Hu’s model | \(\rho\) (g cm−3) | |
m2 = 0.5 | |||||
0.5 | 1.0507 | 0.6662 | 0.6551 | 0.6633 | 1.0542 |
1.0 | 1.0714 | 0.6771 | 0.6689 | 0.6754 | 1.0756 |
1.5 | 1.0902 | 0.6892 | 0.6828 | 0.6881 | 1.0956 |
2.0 | 1.1083 | 0.7004 | 0.6970 | 0.7010 | 1.1146 |
2.5 | 1.1297 | 0.7134 | 0.7116 | 0.7140 | 1.1324 |
3.0 | 1.1424 | 0.7284 | 0.7274 | 0.7275 | 1.1494 |
4.0 | 1.1583 | 0.7544 | 0.7430 | 0.7396 | 1.1653 |
m2 = 1.0 | |||||
0.5 | 1.0907 | 0.7685 | 0.7648 | 0.7836 | 1.0917 |
1.0 | 1.1088 | 0.7825 | 0.7819 | 0.7968 | 1.1110 |
1.5 | 1.1273 | 0.7950 | 0.7989 | 0.8097 | 1.1290 |
2.0 | 1.1436 | 0.8099 | 0.8178 | 0.8238 | 1.1464 |
2.5 | 1.1601 | 0.8272 | 0.8344 | 0.8347 | 1.1622 |
3.0 | 1.1756 | 0.8434 | 0.8530 | 0.8462 | 1.1773 |
m2 = 1.5 | |||||
0.5 | 1.1271 | 0.8906 | 0.8931 | 0.9176 | 1.1271 |
1.0 | 1.1445 | 0.9092 | 0.9138 | 0.9310 | 1.1444 |
1.5 | 1.1613 | 0.9217 | 0.9338 | 0.9430 | 1.1605 |
2.0 | 1.1772 | 0.9518 | 0.9550 | 0.9546 | 1.1758 |
2.5 | 1.1926 | 0.9603 | 0.9764 | 0.9646 | 1.1900 |
m2 = 2.0 | |||||
0.5 | 1.1416 | 1.0246 | 1.0452 | 1.0715 | 1.1604 |
1.0 | 1.1788 | 1.0783 | 1.0690 | 1.0835 | 1.1758 |
1.5 | 1.1943 | 1.0826 | 1.0927 | 1.0934 | 1.1900 |
2.0 | 1.2095 | 1.1095 | 1.1188 | 1.1032 | 1.2035 |
m2 = 2.5 | |||||
0.5 | 1.1968 | 1.2266 | 1.2261 | 1.2531 | 1.1920 |
1.0 | 1.2117 | 1.2549 | 1.2530 | 1.2611 | 1.2054 |
1.5 | 1.2267 | 1.2846 | 1.2803 | 1.2657 | 1.2178 |
m2 = 3.0 | |||||
0.5 | 1.2283 | 1.4415 | 1.4437 | 1.4718 | 1.2223 |
1.0 | 1.2427 | 1.4802 | 1.4735 | 1.4699 | 1.2337 |
m2 = 3.5 | |||||
0.5 | 1.2578 | 1.7161 | 1.7070 | 1.7327 | 1.2516 |
1.0 | 1.2720 | 1.7557 | 1.7407 | 1.7092 | 1.2609 |
m2 = 4.0 | |||||
0.5 | 1.2868 | 2.0785 | 2.0306 | 2.0326 | 1.2802 |
AAD% = 0.79 | AAD% = 1.31 | AAD% = 0.40 | |||
SD = 0.0124 | SD = 0.0199 | SD = 0.0056 | |||