Table 3 Measures of nonplanarity for Re corroles: the Re–N4 displacement (Å), the C8–C9–C11–C12 saddling dihedral (°), and the C5–Re–C15 angle (°).

From: Synthesis and molecular structure of perhalogenated rhenium-oxo corroles

Molecule

Re–N4 (Å)

χC8–C9–C11–C12 (°)

ϕC5–Re–C15 (°)

Re[TPC](O)

0.704

7.2

155.1

Re[Cl8TpCF3PC](O); molecule 1

0.671

15.4

155.1

Re[Cl8TpCF3PC](O); molecule 2

0.659

6.7

154.0

Re[Cl8TpCH3PC](O)

0.671

8.5

157.4

Re[Br8TpFPC](O)

0.668

11.9

152.5

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