Table 2 Suzuki cross–coupling reactions catalyzed by v-SiO2 NRs@Pd nanostructured catalyst.

From: Architecture engineering of nanostructured catalyst via layer-by-layer adornment of multiple nanocatalysts on silica nanorod arrays for hydrogenation of nitroarenes

View full size image

Entry

Substrate

Time (h)

Yields (%)a

1

3

97

2

3

94

3

5

95

4

5

91

5

5

87

  1. Reaction conditions: Aryl halide (0.1 mmol), phenylboronic acid (0.12 eq.), v-SiO2 NRs@Pd nanostructured catalyst (1 mol%), K2CO3 (1.5 eq.), DMF/H2O (5:1), 100 °C. aYields were determined by GC–MS.