Table 2 Differentially presented metabolites in LD vs. PM with two production replicates.
RT | Mass | VIP[1] (muscle) | VIP[2] (replicates) | Metabolitesa | Higher in muscle | Higher in replicate |
|---|---|---|---|---|---|---|
Amino acids | ||||||
9.54 | 156 | 1.92 | 1.47 | 5-Oxoproline | PM | Apr–Sep |
8.68 | 174 | 0.84 | 1.68 | Alanine | LD | July–Jan |
9.08 | 218 | 1.31 | 1.05 | Aminomalonic acid | LD | July–Jan |
9.1 | 232 | 1.32 | 1.13 | Aspartic acid | PM | July–Jan |
9.83 | 329 | 0.07 | 1.07 | Creatinine | July–Jan | |
9.56 | 174 | 0.25 | 1.22 | GABA | Apr–Sep | |
10.26 | 246 | 1.62 | 1.45 | Glutamic acid | PM | Apr–Sep |
7.61 | 174 | 1.57 | 1.41 | Glycine | PM | July–Jan |
15.97 | 159 | 0.6 | 1.09 | Histidine | July–Jan | |
7.48 | 158 | 1.28 | 1.08 | Isoleucine | PM | Apr–Sep |
6.06 | 188 | 0.23 | 1.09 | Leucine | Apr–Sep | |
9.48 | 176 | 1.48 | 1.33 | Methionine | PM | Apr–Sep |
11.75 | 174 | 0.42 | 1.04 | Ornithine | July–Jan | |
10.37 | 218 | 1.4 | 1.13 | Phenylalanine | PM | Apr–Sep |
7.53 | 216 | 1.25 | 0.94 | Proline | PM | July–Jan |
8.09 | 204 | 1.67 | 1.25 | Serine | PM | Apr–Sep |
8.34 | 219 | 1.72 | 1.23 | Threonine | PM | July–Jan |
6.7 | 218 | 1.45 | 1.14 | Valine | PM | Apr–Sep |
Carbohydrates | ||||||
12.28 | 307 | 1.99 | 1.43 | Fructose | LD | Apr–Sep |
12.21 | 103 | 2 | 1.43 | Fructose | LD | Apr–Sep |
13.1 | 333 | 1.4 | 1.19 | Gluconic acid | LD | Apr–Sep |
12.41 | 160 | 1.83 | 1.36 | Glucose | LD | Apr–Sep |
12.53 | 160 | 1.85 | 1.39 | Glucose | LD | Apr–Sep |
12.31 | 160 | 1.96 | 1.43 | Glucose | LD | Apr–Sep |
7.82 | 189 | 0.2 | 1.01 | Glyceric acid | Apr–Sep | |
7.3 | 205 | 1.34 | 1.05 | Glycerol | PM | July–Jan |
17.1 | 204 | 1.31 | 1.03 | Lactose | LD | Apr–Sep |
16.91 | 204 | 1.32 | 1.03 | Lactose | LD | Apr–Sep |
17.41 | 361 | 1.38 | 1.08 | Maltose | LD | Apr–Sep |
17.27 | 361 | 1.44 | 1.1 | Maltose | LD | Apr–Sep |
13.66 | 191 | 1.97 | 1.58 | Myo-inositol | PM | Apr–Sep |
11 | 246 | 0.07 | 1.48 | Carbohydrate 1 | Apr–Sep | |
12.9 | 204 | 1.64 | 1.18 | Carbohydrate 10 | LD | Apr–Sep |
13.25 | 318 | 2.01 | 1.51 | Carbohydrate 11 | PM | Apr–Sep |
14.62 | 315 | 1.82 | 1.35 | Carbohydrate 12 | LD | July–Jan |
14.75 | 204 | 1.65 | 1.26 | Carbohydrate 13 | LD | July–Jan |
14.97 | 315 | 2 | 1.44 | Carbohydrate 15 | LD | Apr–Sep |
14.98 | 387 | 2.01 | 1.44 | Carbohydrate 16 | LD | Apr–Sep |
15.05 | 160 | 1.98 | 1.42 | Carbohydrate 17 | LD | Apr–Sep |
15.15 | 387 | 1.97 | 1.41 | Carbohydrate 18 | LD | Apr–Sep |
15.22 | 204 | 1.63 | 1.27 | Carbohydrate 19 | LD | July–Jan |
11.74 | 204 | 1.63 | 1.25 | Carbohydrate 2 | LD | Apr–Sep |
15.34 | 387 | 1.85 | 1.34 | Carbohydrate 21 | LD | Apr–Sep |
11.77 | 217 | 1.73 | 1.24 | Carbohydrate 3 | LD | July–Jan |
11.85 | 204 | 1.76 | 1.32 | Carbohydrate 4 | LD | Apr–Sep |
11.98 | 217 | 1.16 | 1.1 | Carbohydrate 5 | LD | Apr–Sep |
12.34 | 204 | 1.68 | 1.21 | Carbohydrate 7 | LD | Apr–Sep |
12.66 | 319 | 1.28 | 1.25 | Carbohydrate 8 | PM | Apr–Sep |
12.9 | 217 | 1.47 | 1.09 | Carbohydrate 9 | LD | Apr–Sep |
Lipids | ||||||
15.7 | 205 | 0.65 | 1.12 | 1-O-hexadecylglycerol | Apr–Sep | |
11.39 | 357 | 0.65 | 1.01 | alpha-Glycerophosphoric acid | Apr–Sep | |
15.12 | 117 | 1.49 | 1.2 | Arachidonic acid | Apr–Sep | |
11.13 | 243 | 0.98 | 1.83 | beta-Glycerophosphoric acid | Apr–Sep | |
17.2 | 399 | 0.38 | 1.18 | Glycerol monostearate | ||
16.07 | 218 | 0.66 | 1.2 | Glyceryl 2-palmitate | Apr–Sep | |
17.02 | 218 | 0.16 | 1.1 | Glyceryl 2-stearate | ||
14.2 | 337 | 0.42 | 1.89 | Linoleic acid | Apr–Sep | |
15.24 | 343 | 1.03 | 0.82 | Myristic acid | ||
15.34 | 128 | 0.51 | 1.15 | Oleamide | July–Jan | |
14.22 | 199 | 1.07 | 1.98 | Oleic acid | Apr–Sep | |
13.17 | 117 | 0.54 | 1.99 | Palmitic acid | Apr–Sep | |
11.54 | 299 | 1.52 | 1.12 | Phosphoethanolamine | Apr–Sep | |
14.35 | 341 | 0.85 | 1.14 | Stearic acid | Apr–Sep | |
Purine/pyrimidine | ||||||
6.54 | 166 | 1.41 | 1.07 | 3-Hydroxy-6-methylpyridine | LD | |
7.9 | 241 | 1.55 | 1.55 | 5-Hydroxymethyluracil | PM | Apr–Sep |
17.42 | 236 | 0.86 | 1.6 | 5′-Methylthioadenosine | July–Jan | |
19.13 | 169 | 1.19 | 1.44 | Adenosine 5′-monophosphate | PM | July–Jan |
17.3 | 324 | 1.66 | 1.24 | Guanosine | PM | July–Jan |
11.74 | 265 | 1.72 | 1.37 | Hypoxanthine | PM | Apr–Sep |
16.32 | 230 | 1.44 | 1.08 | Inosine | PM | July–Jan |
18.65 | 169 | 1.27 | 1.27 | Uridine 5′-monophosphate | PM | July–Jan |
Organic acid | ||||||
6.11 | 117 | 1.3 | 1.07 | 2-Hydroxybutyric acid | PM | July–Jan |
9.68 | 247 | 1.67 | 1.49 | 2-Hydroxyglutaric acid | PM | Apr–Sep |
6.62 | 131 | 0.99 | 1.06 | 3-Hydroxy-3-methylbutyric acid | PM | Apr–Sep |
6.86 | 233 | 1.65 | 1.33 | 4-Hydroxybutyric acid | PM | Apr–Sep |
7.91 | 245 | 1.55 | 1.37 | Fumaric acid | PM | Apr–Sep |
12.76 | 361 | 1.08 | 0.99 | Galactonic acid 1,4-lactone | LD | July–Jan |
5.23 | 177 | 1.43 | 1.05 | Glycolic acid | PM | |
8.88 | 218 | 0.86 | 1.52 | Homoserine | July–Jan | |
9.21 | 233 | 1.69 | 1.65 | Malic acid | PM | Apr–Sep |
5.36 | 217 | 1.32 | 1.26 | Pyruvic acid | PM | Apr–Sep |
7.63 | 247 | 1.68 | 1.33 | Succinic acid | PM | July–Jan |
7.14 | 189 | 0.54 | 1.62 | Urea | Apr–Sep | |
12.7 | 332 | 0.27 | 1.59 | Ascorbic acid | July–Jan | |
Others | ||||||
11.65 | 328 | 0.93 | 1.11 | Ammeline | Apr–Sep | |
10.23 | 255 | 1.18 | 0.99 | Melamine | PM | |
10.44 | 117 | 0.53 | 1.18 | N.I 5 | ||
12.52 | 305 | 1.6 | 1.25 | N.I 6 | ||
12.95 | 291 | 1.27 | 0.94 | Pantothenic acid | PM | |
