Table 1 The effect of various conditions on the methylphenyl sulfide to sulfoxide for 4 h in the presence of H2O2 as an oxidant and water as solventa.
Entry | Amount of catalyst (μM) | Oxidant amount (mmol) | Conversion (%) | Selectivity (%) |
|---|---|---|---|---|
1 | – | 0.4 | 11 | 100 |
2 | 22.5 | 0.4 | 49 | 99 |
3 | 44.9 | 0.4 | 81 | 96 |
4 | 67.4 | 0.4 | 100 | 92 |
5 | 67.4 | 0.3 | 84 | 97 |
6 | 67.4 | 0.2 | 58 | 98 |
7 | 67.4 | 0.1 | 37 | 100 |