Table 2 Oxidation reactions catalyzed by 1^a.

Entry	Conversion (%)^b	Selectivity (%)^c	TON (TOF(h⁻¹))
1	100	92	2967 (741)
2	91	94	2700 (675)
3	99	95	2938 (734)
4	100	93	2967 (741)
5	100	95	2967 (741)
6	75	97	2226 (556)
7	89	96	2641 (660)
8	71	99	2107 (527)
9	85	98	2522 (631)
10	65	99	1929 (482)
11	80	100	2374 (593)
12	58	100	1721 (430)
13	60	78	1780 (445)
14	53	100	1573 (393)

^aReaction conditions; four hours; catalyst (67.4 μM), H₂O (1 mL), substrate (0.2 mmol), H₂O₂ (0.4 mmol), at room temperature.
^bThe GC conversion (%) is measured relative to the starting substrate.
^cSelectivity to sulfoxide = (sulfoxide %/(sulfoxide% + sulfone%)) × 100; Selectivity to benzaldehyde = (aldehyde%/(aldehyde% + carboxylic acid%)) × 100; Selectivity to epoxide = (epoxide%/(epoxide% + aldehyde%)) × 100; TON = mol product/mol catalyst; TOF = TON/time of reaction (4 h).

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