Table 3 Oxidation of organic substrates with different nano-iron oxide catalysts.

From: Ultra-small and highly dispersive iron oxide hydroxide as an efficient catalyst for oxidation reactions: a Swiss-army-knife catalyst

Entry

Catalyst

Condition

Conversion (%)

Selectivity (%)

References

1

Ultra-small FeOOH

67.4 μmol catalyst, 0.4 mmol H2O2, 0.2 mmol substrate, room temperature, 4 h

89

96

This work

2

Bulk α-Fe2O3

1 mol% of catalyst, 10 mmol of substrate, 10 mmol H2O2, 75 °C, 12 h

5

99

12

3

Bulk γ-Fe2O3

1 mol% of catalyst, 10 mmol of substrate, 10 mmol H2O2,75 °C, 12 h

5

99

12

4

Nano γ-Fe2O3

1 mol% of catalyst, 10 mmol of substrate, 15 mmol H2O2, 75 °C, 12 h

72

66

12