Table 2 Experimental and computed wavelengths, MO contributions (≥ %10), and oscillator strength (f) involved in each transition for MTBH4, MTBH6, and MTBH0. Phrase sh stands for shoulder.
Exp | Com | |||
|---|---|---|---|---|
λ (nm, ev) | Λ (nm, ev) | Main transitions | f | |
MTBH4 | 440 (2.82) | 451 (2.74) | Ho − 2 → Lu (77%), Ho − 3 → Lu (10%) | 0.43 |
355 (3.49, sh) | 382 (3.25) | Ho − 7 → Lu (51%), Ho − 12 → Lu (18) | 0.13 | |
364 (3.40) | Ho − 11 → Lu (41%), Ho − 12 → Lu (14%), Ho − 13 → Lu (22%) | 0.11 | ||
339 (3.66) | Ho − 15 → Lu (59%), | 0.09 | ||
277 (4.48) | 284 (4.37) | Ho → Lu + 2 (71%), Ho − 23 → Lu (11%) | 0.13 | |
MTBH6 | 440 (2.82) | 443 (2.80) | Ho → Lu (89%) | 0.47 |
400 (3.10) | Ho − 2 → Lu (81%) | 0.05 | ||
355 (3.49, sh) | 363 (3.41) | Ho − 7 → Lu (84%) | 0.05 | |
346 (3.58) | Ho − 8 → L (34%), Ho − 9 → Lu (16%), Ho − 11 → Lu (38%) | 0.05 | ||
343 (3.61) | Ho − 8 → Lu (13%), Ho − 9 → Lu (69%) | 0.05 | ||
277 (4.48) | 286 (4.33) | Ho → Lu + 1 (79%), Ho → uL + 2 (13%) | 0.06 | |
MTBH0 | 606 (2.03) | 609 (2.04) | Ho − 1 → Lu (68%), Ho → Lu (32%) | 0.13 |
587 (2.11) | Ho → Lu (51%), Ho − 1 → Lu (25%), Ho − 2 → Lu (23%) | 0.30 | ||
585 (2.12) | Ho − 2 → Lu (75%), Ho → Lu (17%) | 0.14 | ||
396 (3.13) | 393 (3.15) | Ho − 11 → Lu (42%), Ho − 18 → Lu (25%) | 0.14 | |
369 (3.36) | Ho → Lu (68%), Ho − 18 → Lu (15%) | 0.09 | ||
347 (3.57) | Ho → Lu + 2 (92%) | 0.18 | ||
310 (4.00) | 295 (4.20) | Ho → Lu + 4 (91%) | 0.14 | |
