Table 7 R2 and K values for various kinetic models for UPKC at pH 3 and Temperatures 30 °C, 35 °C and 40 °C.
Ads | pH | Temp (°C) | Initial Conc. (mg/l) | First order | Pseudo first order | Second order | Pseudo second order | Intra particle diffusion | |||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
k (min−1) | R2 | k (min−1) | R2 | k (l/mg min) | R2 | k (g/mg min) | R2 | k (g/mg min−1) | R2 | ||||
UCPKC | 3 | 30 | 10 | 0.0761 | 0.9198 | 1.4652 | 0.8627 | 0.1047 | 0.9397 | 9.7948 | 0.4123 | −0.5892 | 0.9384 |
30 | 0.2378 | 0.9195 | 1.5084 | 0.8909 | 0.0421 | 0.9072 | 0.8288 | 0.9555 | 5.1751 | 0.8562 | |||
50 | 0.1671 | 0.9320 | 2.6435 | 0.9164 | 0.0235 | 0.9418 | 0.7315 | 0.9786 | 4.3126 | 0.9683 | |||
70 | 0.2506 | 0.5009 | 1.8936 | 0.6490 | 0.0184 | 0.5286 | 0.2014 | 0.9968 | 12.1198 | 0.6033 | |||
100 | 0.3113 | 0.9382 | 1.6020 | 0.9015 | 0.0136 | 0.9404 | 0.0658 | 0.9989 | 25.4036 | 0.9355 | |||
120 | 0.1662 | 0.4526 | 4.6450 | 0.7549 | 0.0099 | 0.4761 | 0.2504 | 0.9871 | 12.2134 | 0.5614 | |||
35 | 10 | 0.2036 | 0.9307 | 3.3036 | 0.7414 | 0.1202 | 0.9477 | 3.1922 | 0.9665 | 0.7739 | 0.9555 | ||
30 | 0.4320 | 0.5289 | 1.2575 | 0.7236 | 0.0515 | 0.5659 | 0.2172 | 0.9990 | 8.7344 | 0.6397 | |||
50 | 0.2469 | 0.7483 | 2.5590 | 0.9799 | 0.0256 | 0.7551 | 0.4160 | 0.9904 | 6.6615 | 0.8627 | |||
70 | 0.3518 | 0.8094 | 1.8684 | 0.8283 | 0.0203 | 0.8289 | 0.1272 | 0.9968 | 18.4895 | 0.8651 | |||
100 | 0.3737 | 0.9284 | 1.8098 | 0.8498 | 0.0145 | 0.9306 | 0.0500 | 0.9992 | 29.7023 | 0.9475 | |||
120 | 0.3344 | 0.8725 | 4.4502 | 0.7619 | 0.0116 | 0.8805 | 0.0619 | 0.9993 | 30.9806 | 0.9563 | |||
40 | 10 | 0.2653 | 0.9470 | 3.5678 | 0.6810 | 0.1234 | 0.9240 | 2.4143 | 0.9412 | 1.3579 | 0.9479 | ||
30 | 0.5332 | 0.8652 | 3.4724 | 0.7078 | 0.0567 | 0.8770 | 0.2089 | 0.9969 | 11.2197 | 0.8931 | |||
50 | 0.2423 | 0.9104 | 3.5228 | 0.8265 | 0.0250 | 0.9216 | 0.5162 | 0.9795 | 5.3090 | 0.9578 | |||
70 | 0.3787 | 0.5623 | 2.5603 | 0.6716 | 0.0210 | 0.6294 | 0.1813 | 0.9935 | 15.4148 | 0.6344 | |||
100 | 0.5578 | 0.7210 | 1.3261 | 0.9457 | 0.0175 | 0.7310 | 0.0167 | 0.9999 | 41.3680 | 0.8469 | |||
120 | 0.4517 | 0.6652 | 2.0127 | 0.6629 | 0.0131 | 0.6868 | 0.0391 | 0.9985 | 40.6005 | 0.7361 | |||