Table 1 Paint stratigraphy samples. Pigment density, observed through optical microscopy, is categorized as l = low, m = medium or h = high, for each type of pigment: L = lead red, Vi = viridian, U = ultramarine, Ve = vermilion and C = chrome yellow. The average diameter of the crystals, in micrometers, is indicated in parenthesis next to the pigment symbols. Analysis symbology: OM = optical microscopy, R = Raman spectroscopy, EDX = energy dispersive X ray spectroscopy, UV = fluorescence microscopy and FTIR-ATR = Fourier transform infrared - attenuated total reflectance spectroscopy. For FTIR-ATR analysis, samples were not embedded. The rest of the analyses were carried out on cross-sections of samples.

From: Revealing time’s secrets at the National Theatre of Costa Rica via innovative software for cultural heritage research

Painting

Sample name

Visible colour

Grid location

Pigments density

Crystal average diameter (\(\upmu m\))

Analysis

Musas I

M1-45B

Dark blue

45

Layer 1: Ve(h), U(m), C(m)

Ve(4.7), U(2.0), C(1.2)

MO, R, EDX

Layer 2: C(m), U(m)

M1-54P

Pink

54

Layer 1: Ve(m), L(l)

Ve(1.4), L(21)

MO, R

M1-54R

Red

54

Layer 1: Ve(h), C(m)

 

MO, R, SEM, UV

M1-58W

White

58

Layer 1: C(l)

 

MO, R, EDX

M1-60W

White

60

Layer 1: C(l)

 

MO, R

Layer 2: U(l), C(l)

 

M1-75W

White

75

Layer 1: Ve(l), C(l)

C(7.7), U(3.4)

MO, R, SEM, EDX, FTIR-ATR, UV

Layer 2: C(h), U(m)

Musas II

M2-27B

Light blue

27

Layer 1: U(m)

 

MO, R, UV

Layer 2: U(m), C(m)

M2-31W

White

31

Layer 1: Ve(l)

 

MO, R, EDX, FTIR-ATR, UV

Layer 2: U(h), C(h)

M2-33Br

Brown

33

Layer 1: Ve(m), U(l), C(l)

 

MO, R, EDX, UV

Layer 2: U(m), C(m)

M2-39B

Dark blue

39

Layer 1: U(m), C(m), Ve(l)

U(4.7), C(1.4), Ve(2.3)

MO, R, EDX, UV

M2-63W

White

63

Layer 1: C(h), U(h)

 

R

M2-69P

Pink

69

Layer 1: Vi(l), Ve(l),L(l), U(l),C(l)

Vi(5.1), Ve(3.0), L(0.6), U(2.5), C(0.6)

MO, R

M2-70L

Light purple

70

Layer 1: Ve(m), U(m), C(l)

 

R

Layer 2: C(h), U(h)

M2-73Br

Brown

73

Layer 1: U(m), C(m)

C(4.8), U(4.13)

MO, R

Layer 2: U(m), C(m)

M2-83Br

Brown

83

  

FTIR-ATR