Table 2 Mizoroki–Heck reaction between iodobenzene and n-butyl acrylate catalyzed by γ-Fe2O3@MBD/Pd-Co containing different ratios of Pd:Co in water.

From: A new nanomagnetic Pd-Co bimetallic alloy as catalyst in the Mizoroki–Heck and Buchwald–Hartwig amination reactions in aqueous media

Entry[a]

Pd[a] (mmol g−1)

Co[a] (mmol g−1)

molar ratio Pd:Co

Pd (mol%)

Time (min)

Isolated yield[b] (%)

1

0.593

3.44

1:5.8

0.04

540

95

2

0.751

3.15

1:4.2

0.05

25

99

3

1.61

1.29

1:0.8

0.1

20

99

  1. [a] Based on ICP-OES analysis, [b] Reaction conditions: iodobenzene (1 mmol), n-butyl acrylate (1.3 mmol), base (2 mmol), water (1 mL), 60 °C, catalyst (0.00066 g).
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