Table 3 Mizoroki–Heck reaction of various haloarenes with olefins promoted by γ-Fe2O3@MBD/Pd-Co in aqueous media.

From: A new nanomagnetic Pd-Co bimetallic alloy as catalyst in the Mizoroki–Heck and Buchwald–Hartwig amination reactions in aqueous media

  1. [a] Reaction conditions: catalyst (0.05 mol% based on the Pd content), haloarene (1 mmol), alkene (1.3 mmol), Et3N (2 mmol), water (1 mL), 60 °C. Trans-isomer was identified based on 3JH-H value of 16.0–16.4 Hz for vinylic hydrogens in the 1H NMR of the products (Figure S1–S13).