Table 2 Identification of the composition of thermally degraded products by GC–MS.
From: Liquid fuel oil produced from plastic based medical wastes by thermal cracking
Types of composition | Name of constituents | Chemical formula | Boiling point (°C) | GC–MS Data | |
|---|---|---|---|---|---|
Constituent (%, peak area) | Retention time | ||||
Alkane | 3,3 dimethyl Octane | C10H22 | 161 | 2.54 | 4.342 |
Dodecane | C12H26 | 216 | 0.71 | 6.037 | |
Tridecane | C13H28 | 234 | 2.53 | 7.039 | |
Tetradecane | C14H30 | 255 | 2.22 | 8.117 | |
Pentadecane | C15H32 | 270 | 2.47 | 9.247 | |
Heptadecane | C17H36 | 302 | 1.41 | 11.526 | |
Eicosane | C20H42 | 343 | 0.77 | 15.719 | |
Heneicosane | C21H44 | 356 | 1.36 | 12.633, 13.703 | |
Hexacosane | C26H54 | 412 | 2.27 | 10.393 | |
Cycloalkane | 4-cyclohexylDecane | C16H32 | – | 1.57 | 6.917 |
1,1 (1,4-butandiyl) bis-Cyclopentane | C14H26 | – | 0.99 | 7.908 | |
Alkene | 1-Dodecene | C12H24 | 213 | 0.57 | 5.965 |
1-Tridecene | C13H26 | 233 | 1.35 | 6.958 | |
1-Tetradecene | C14H28 | 251 | 2.93 | 8.033 | |
1-Pentadecene | C15H30 | 268 | 4.48 | 9.164, 10.311 | |
1-Nonadecene | C19H38 | – | 0.82 | 13.642 | |
7-methyl-1-Undecene | C12H24 | – | 0.52 | 4.933 | |
Alcohol | 2-Ethyl-1-hexanol | C8H18O | 184 | 3.57 | 4.55, 4.442, 4.502 |
1-Heptanol, 2,4-diethyl- | C11H24O | – | 2.12 | 7.225 | |
11-Methyldodecanol | C13H28O | 268 | 7.6 | 7.133, 7.313 | |
n-Pentadecanol | C15H32O | 270 | 1.36 | 11.45 | |
Ester | Hexadecanoic acid, ethyl ester | C18H36O2 | 377 | 3.71 | 14.675 |
Ethyl 14-methyl-hexadecanoate | C18H36O2 | – | 2.23 | 12.566, 16.622 | |
Ethyl 9-hexadecenoate | C18H34O2 | 356 | 1.41 | 14.483 | |
(E)-9-Octadecenoic acid ethyl ester | C20H38O2 | 217 | 0.9 | 16.399 | |
Isodecyl methacrylate | C14H26O2 | 120 | 0.86 | 4.975 | |
Hexadecanoic acid, methyl ester | C17H34O2 | 417 | 0.73 | 13.983 | |
Phenol | Phenol | C6H6O | 182 | 1.89 | 4.175, 4.099 |
p-Cumenol | C9H12O | – | 1.43 | 6.117, 6.336 | |
Phthalate | 1,3-Benzene dicarboxylic acid, bis(2-ethylhexyl) ester | C24H38O4 | 400 | 40.02 | 19.792 |
Bis(2-ethylhexyl) phthalate | C24H38O4 | 385 | 2.11 | 19.683, 19.475 | |