Table 4 Kinetic model parameters for removing Cr(VI) and Cu(II) using SA/CMC-ZFN.

From: Portable SA/CMC entrapped bimetallic magnetic fly ash zeolite spheres for heavy metals contaminated industrial effluents treatment via batch and column studies

Metal ion

Metal ion concentration (mg/L)

\({\text{Q}}_{{\text{e}}}\), exp (mg/g)

Pseudo first order (PFO)

\({\text{Log(Q}}_{{\text{e}}} - {\text{Q}}_{{\text{t}}} {)} = {\text{Log}}\,{\text{qQ}}_{{\text{e}}} - \left( {\frac{{{\text{k}}_{1} }}{2.03}} \right){\text{t}}\)

Pseudo second order (PSO)

\(\frac{{\text{t}}}{{{\text{Q}}_{{\text{t}}} }}{ } = { }\frac{1}{{{\text{k}}_{2} {\text{Q}}_{{\text{e}}}^{2} }}{ } + \left( {\frac{1}{{{\text{Q}}_{{\text{e}}} }}} \right){\text{t}}\)

\({\text{Q}}_{{\text{e}}}\)(mg/g)

k1 (min−1)

R2

\({\text{Q}}_{{\text{e}}}\)(mg/g)

k2(g/mg min)

R2

Cr(VI)

20

8.2

5.27

0.003

0.9806

8.54

0.001

0.9988

40

9.11

6.02

0.003

0.9783

9.81

0.001

0.9984

60

9.9

6.63

1.89

0.9917

10.5

0.001

0.9991

Cu(II)

50

46.04

53.5

0.003

0.9881

51.54

1.32E−04

0.9986

100

56.32

37.7

0.003

0.9796

67.11

6.57E−05

0.9949

150

62.83

49.72

0.004

0.9906

68.96

1.31E−04

0.9992