Table 1 Kinetics and isotherms parameters for As (III) and Cd(II) adsorption on Fh@BC (25 °C) in the single solution or binary solution (with a simultaneous or sequential addition).
Parameters | Treatment | Cd | As | ||||||
|---|---|---|---|---|---|---|---|---|---|
Cd + As | Cd and As | As + Cd | Cd | Cd + As | Cd and As | As + Cd | As | ||
PFO | qe (mg g−1) | 3.147 | 2.309 | 2.022 | 2.865 | 1.080 | 1.442 | 1.578 | 1.356 |
k1 (h−1) | 0.642 | 0.909 | 0.903 | 0.891 | 1.055 | 0.882 | 0.615 | 1.165 | |
R2 | 0.918 | 0.954 | 0.963 | 0.973 | 0.910 | 0.892 | 0.833 | 0.923 | |
PSO | qe (mg g−1) | 3.322 | 2.426 | 2.197 | 3.112 | 1.190 | 1.532 | 1.684 | 1.481 |
k2(g (mg h)−1) | 0.325 | 0.698 | 0.679 | 0.463 | 1.294 | 0.954 | 0.566 | 1.200 | |
R2 | 0.967 | 0.989 | 0.985 | 0.994 | 0.965 | 0.960 | 0.923 | 0.968 | |
Langmuir | KL (L mg−1) | 0.021 | 0.068 | 0.007 | 0.026 | 0.034 | 0.041 | 0.017 | 0.016 |
Qm (mg g−1) | 23.712 | 14.751 | 19.958 | 18.181 | 6.838 | 13.550 | 22.809 | 18.381 | |
R2 | 0.966 | 0.890 | 0.973 | 0.990 | 0.913 | 0.924 | 0.978 | 0.970 | |
Freundlich | KF(mg(1−n) Ln g−1) | 1.763 | 2.941 | 0.406 | 1.420 | 0.721 | 1.609 | 1.033 | 0.751 |
n | 2.127 | 3.178 | 1.567 | 2.181 | 2.412 | 2.483 | 1.807 | 1.804 | |
R2 | 0.999 | 0.994 | 0.982 | 0.988 | 0.808 | 0.896 | 0.934 | 0.919 | |