Table 6 Computed thermodynamic properties.

From: Experimental solubility and thermodynamic modeling of empagliflozin in supercritical carbon dioxide

Model

Thermodynamic property

Total entalpy, ΔHtotal (kJ/mol)

Enthalpy of sublimation, ΔHsub (kJ/mol)

Enthalpy of solvation,\(\Delta H_{sol}\) (kJ/mol)

Chrastil model

30.548a

 

− 19.105d

Reformulated Chrastil model

22.496b

 

− 27.157e

Bartle et al., model

 

49.653c (approximate value)

 
  1. aObtained with Chrastil model
  2. bObtained with Reformulated Chrastil model
  3. cObtained with Bartle et al.
  4. dObtained as a result of difference between the ΔHsubc and ΔHtotala.
  5. eObtained as a result between the ΔHsubc and ΔHtotalb.
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