Table 1 Kinetic parameters of exothermic reactions of the ALG and the nAl.
Sample | Ea/(kJ mol−1) | lg(A/s−1) | R | The most possible functions | Kinetic equation |
|---|---|---|---|---|---|
ALG | 442.74 | 25.17 | 0.982 | \(\frac{2}{3}(1 - \alpha )^{\frac{2}{3}} [1 - (1 - \alpha )^{\frac{1}{3}} ]^{ - 1}\) | \(\begin{gathered} 10^{24.99} \times (1 - \alpha )^{\frac{2}{3}} [1 - (1 - \alpha )^{\frac{1}{3}} ]^{ - 1} \hfill \\ \times e^{ - 53252.3/T} \hfill \\ \end{gathered}\) |
nAl | 458.02 | 25.57 | 0.963 | \(\frac{1}{3}(1 - \alpha )[ - \ln (1 - \alpha )]^{ - 2}\) | \(\begin{gathered} 10^{25.09} \times (1 - \alpha )[ - \ln (1 - \alpha )]^{ - 2} \hfill \\ \times e^{ - 55090.2/T} \hfill \\ \end{gathered}\) |
