Table 2 Major elemental compositions (wt%) obtained by the XRF analysis of the samples from Mbanza Kongo (MBK), Kindoki (KDK) and Ngongo Mbata (NBC).
Sample no. | Type | Na2O | MgO | Al2O3 | SiO2 | P2O5 | K2O | CaO | TiO2 | MnO | Fe2O3 |
|---|---|---|---|---|---|---|---|---|---|---|---|
KDK_S.12 | KDK | 0.18 | 8.40 | 15.90 | 53.20 | 0.58 | 2.50 | 0.37 | 0.82 | 0.03 | 3.98 |
KDK_S.13 | KDK | 0.14 | 9.81 | 15.60 | 49.70 | 0.98 | 1.69 | 0.16 | 0.61 | < 0.01 | 3.90 |
KDK_S.15 | KDK | 0.15 | 9.61 | 12.60 | 61.00 | 0.17 | 1.90 | 0.07 | 0.61 | < 0.01 | 1.91 |
MBK_S.6 | A | 0.78 | 3.71 | 16.70 | 49.90 | 0.08 | 3.44 | 2.47 | 0.84 | 0.08 | 8.50 |
MBK_S.11 | A | 0.44 | 1.64 | 16.20 | 50.40 | 1.86 | 3.80 | 1.23 | 0.91 | 0.05 | 7.79 |
KDK_S.6 | A | 1.40 | 2.98 | 16.90 | 51.60 | 0.04 | 4.44 | 3.06 | 0.78 | 0.06 | 8.79 |
KDK_S.8 | A | 0.80 | 2.92 | 17.50 | 49.40 | 0.04 | 3.74 | 3.29 | 0.75 | 0.17 | 8.63 |
NBC_S.3 | A | 0.37 | 5.16 | 17.10 | 53.90 | 0.24 | 0.14 | 1.57 | 0.65 | 1.25 | 7.57 |
NBC_S.4 | A | 1.20 | 4.59 | 15.60 | 48.50 | 0.60 | 0.15 | 6.09 | 0.62 | 0.16 | 12.00 |
NBC_S.5 | A | 0.78 | 3.22 | 17.40 | 49.50 | 0.78 | 3.73 | 2.07 | 0.84 | 0.10 | 8.44 |
MBK_S.9 | C | 1.69 | 2.85 | 16.80 | 46.10 | 1.35 | 1.18 | 4.68 | 1.50 | 0.07 | 10.40 |
MBK_S.14 | C | 0.13 | 13.90 | 7.12 | 66.90 | 0.29 | 0.43 | 0.31 | 0.19 | 0.01 | 2.12 |
MBK_S.17 | C | 0.35 | 0.35 | 18.70 | 60.20 | 0.80 | 2.84 | 0.18 | 0.83 | n.d. | 7.68 |
MBK_S.21 | C | 0.21 | 0.64 | 15.30 | 67.10 | 0.89 | 0.99 | 0.57 | 0.68 | 0.04 | 5.16 |
KDK_S.17 | C | 0.44 | 2.87 | 15.10 | 61.80 | 0.08 | 0.73 | 0.19 | 0.85 | 0.01 | 5.01 |
KDK_S.19 | C | 0.66 | 5.03 | 16.70 | 49.20 | 0.07 | 3.90 | 3.20 | 0.74 | 0.02 | 9.81 |
KDK_S.20 | C | 0.19 | 20.70 | 5.55 | 58.00 | 0.64 | 0.33 | 0.21 | 0.19 | n.d. | 2.13 |
NBC_S.11 | C | 0.37 | 0.61 | 16.40 | 61.70 | 1.74 | 0.54 | 0.27 | 0.53 | 0.01 | 2.61 |
NBC_S.12 | C | 0.20 | 0.70 | 16.30 | 70.10 | 0.43 | 0.41 | 0.17 | 0.54 | 0.01 | 3.22 |
NBC_S.14 | C | 0.21 | 0.53 | 14.90 | 62.50 | 1.74 | 0.25 | 0.29 | 0.78 | 0.02 | 3.06 |
MBK_S.4 | D | 3.01 | 0.44 | 16.80 | 55.80 | 0.20 | 4.10 | 1.42 | 3.35 | 0.20 | 6.36 |
MBK_S.15 | D | 1.64 | 2.92 | 16.50 | 51.60 | 0.78 | 1.29 | 4.14 | 1.17 | 0.17 | 10.00 |
MBK_S.19 | D | 1.14 | 7.55 | 9.63 | 52.80 | 1.00 | 0.86 | 6.09 | 0.73 | 0.21 | 10.30 |
MBK_S.22 | D | 2.20 | 0.52 | 15.40 | 62.90 | 0.39 | 2.80 | 2.21 | 0.78 | 0.05 | 5.14 |
MBK_S.25 | D | 1.99 | 0.98 | 17.70 | 54.70 | 0.75 | 2.78 | 1.65 | 0.90 | 0.19 | 7.53 |
KDK_S.1 | D | 2.65 | 0.37 | 17.40 | 54.60 | 0.15 | 4.17 | 1.10 | 2.63 | 0.15 | 6.40 |
KDK_S.4 | D | 4.28 | 0.47 | 18.20 | 56.70 | 0.17 | 3.34 | 0.90 | 1.94 | 0.13 | 5.20 |
KDK_S.5 | D | 4.11 | 0.35 | 18.70 | 55.80 | 0.20 | 3.51 | 0.86 | 1.95 | 0.13 | 5.27 |
NBC_S.16 | D | 2.86 | 0.43 | 17.40 | 52.60 | 1.34 | 4.79 | 1.10 | 3.09 | 0.17 | 6.17 |
NBC_S.17 | D | 2.37 | 0.66 | 16.70 | 54.20 | 1.60 | 2.35 | 2.51 | 1.15 | 0.10 | 6.82 |
NBC_S.18 | D | 2.96 | 0.59 | 18.10 | 56.50 | 0.53 | 4.17 | 1.40 | 2.86 | 0.18 | 6.22 |
NBC_S.20 | D | 4.72 | 0.45 | 18.30 | 51.90 | 1.10 | 2.33 | 1.60 | 2.00 | 0.96 | 6.81 |
NBC_S.22 | D | 2.42 | 1.35 | 16.90 | 52.80 | 1.36 | 2.40 | 2.28 | 0.86 | 0.08 | 7.43 |
NBC_S.23 | D | 1.00 | 3.57 | 17.80 | 44.10 | 1.70 | 0.28 | 4.77 | 1.49 | 0.26 | 12.90 |
NBC_S.24 | D | 3.93 | 1.16 | 17.30 | 46.40 | 1.85 | 2.19 | 1.73 | 1.52 | 0.06 | 9.99 |