Table 6 Determined CVs of non-internal standard and internal standard LA-ICP-MS methods.

From: Bismuth fire assay preconcentration and empirical coefficient LA-ICP-MS for the determination of ultra-trace Pt and Pd in geochemical samples

 

I195Pt/cps

I105Pd/cps

I109Ag/cps

I195Pt /I109 Ag

I105Pd /I109 Ag

1

4.43 × 103

3.52 × 103

5.82 × 108

7.61 × 10–6

6.04 × 10–6

2

4.77 × 103

3.92 × 103

6.46 × 108

7.38 × 10–6

6.07 × 10–6

3

4.65 × 103

3.74 × 103

6.16 × 108

7.55 × 10–6

6.07 × 10–6

4

4.26 × 103

3.56 × 103

5.82 × 108

7.31 × 10–6

6.12 × 10–6

5

4.29 × 103

3.59 × 103

5.73 × 108

7.48 × 10–6

6.26 × 10–6

6

4.59 × 103

3.47 × 103

5.82 × 108

7.88 × 10–6

5.96 × 10–6

7

4.22 × 103

3.53 × 103

5.87 × 108

7.20 × 10–6

6.01 × 10–6

8

4.29 × 103

3.46 × 103

5.74 × 108

7.47 × 10–6

6.04 × 10–6

9

4.90 × 103

3.96 × 103

6.17 × 108

7.94 × 10–6

6.41 × 10–6

10

3.91 × 103

3.31 × 103

5.65 × 108

6.92 × 10–6

5.86 × 10–6

Average

4.43 × 103

3.61 × 103

5.93 × 108

7.47 × 10–6

6.08 × 10–6

CVs/%

6.68

5.71

4.29

4.05

2.54