Table 1 Compositional profile of R. officinalis hexane extract as analysed by GC-MS.

From: Rosmarinus officinalis L. hexane extract: phytochemical analysis, nanoencapsulation, and in silico, in vitro, and in vivo anti-photoaging potential evaluation

No

RT (min)

RI expa

RI litb

Metabolitec

Relative percentile

1

7.07

914

914

α-Pinene

1.73

2

7.52

929

929

Camphene

0.46

3

7.7

936

937

2,4(10)-Thujadiene

0.1

4

8.39

960

960

β-Pinene

0.13

5

9.45

998

998

δ 3-carene

0.08

6

9.93

1013

1013

p-Cymene

0.07

7

10.05

1017

1017

Limonene

0.4

8

10.11

1019

1019

Eucalyptol

1.63

9

12.34

1089

1089

Linalool

0.45

10

13.73

1133

1133

Camphor

2.07

11

14.32

1152

1152

Pinocarvone

0.12

12

14.42

1155

1155

Borneol

1.07

13

14.68

1163

1162

Isopinocamphone

0.17

14

15.22

1180

1180

α-Terpineol

0.21

15

15.59

1192

1196

Isoborneol

0.09

16

15.77

1198

1198

Verbenone

2.08

17

16.78

1233

1234

cis-Myrtanol

0.21

18

18.02

1276

1276

Bornyl acetate

0.31

19

21.8

1408

1408

Caryophyllene

0.2

20

42.19

2368

2300

Tricosane

0.21

21

43.84

2467

2400

Tetracosane

0.27

22

44.78

2528

2525

Diisooctyl phthalate

0.19

23

45.42

2569

2500

Pentacosane

0.43

24

46.93

2666

2600

Hexacosane

0.8

25

48.39

2760

2700

Heptacosane

0.65

26

49.83

2853

2800

Octacosane

3.07

27

51.18

2939

2865

2-methyloctacosane

0.9

28

52

2992

2965

2-Methylnonacosane

0.35

29

52.53

3026

3000

Triacontane

6.73

30

53.29

3075

3112

α-Tocopherol

0.34

31

53.49

3087

3015

3,7-dimethyl-nonacosane

0.54

32

53.83

3110

3100

Hentriacontane

1.34

33

54.58

3157

3120

n-Octacosanol

0.21

34

54.73

3167

3100

Hentriacontane

1.26

35

55.36

3208

3200

Dotriacontane

16.21

36

56.34

3270

3225

16-Methyldotriacontane

0.36

37

56.56

3285

3235

12-Methyldotriacontane

1.7

38

56.69

3294

3337

β-Amyrin

10.4

39

56.99

3313

3300

Tritriacontane

1.11

40

57.1

3319

3337

β-Amyrin

3.95

41

57.57

3350

3376

α-Amyrin

20.64

42

58

3377

3376

α-Amyrin

3.79

43

58.19

3389

3338

15-Methyltritriacontane

0.71

44

58.98

3440

3400

Tetratriacontane

5.11

45

59.35

3464

3384

Lupenone

0.67

46

62.4

3660

3525

Lupeol acetate

4.91

47

62.62

3674

3629

Betulinaldehyde

0.86

% Total Identified

99.29

% Monoterpenes

2.97

% Oxygenated monoterpenes

8.41

% Sesquiterpenes

0.2

% Hydrocarbons

41.75

% Triterpenoids

45.22

Others

0.74

  1. aRetention index calculated experimentally on Rtx-5MS column relative to C8-C28 n-alkanes series.
  2. bCorresponding Kovats retention index from literature and spectral databases.
  3. cIdentification based on comparing retention indices (RI) and mass spectral data (MS) with those found in NIST Mass Spectral Library (2011), Wiley Registry of Mass Spectral Data (8th edition) and reported in literature.