Table 3 Hyperfine parameters from Mӧssbauer spectra (Fig. 10).

PCT9R

5

D₂²⁺/D1

11

–

1.25(5)

2.81

D₁³⁺/C1

55

–

0.44(3)

0.65

S₂/B1

26

49.7(3)

0.40(5)

−0.17

S₁/A1

8

52.2(4)

0.40(5)

0.00

80

DC/E2

7

–

0.20(5)

0.89

D₂²⁺/D2

11

–

1.33(5)

2.45

D₁³⁺/C2

57

–

0.38(4)

0.72

S₂/B2

19

47.4(3)

0.40(5)

−0.29

S₁/A2

6

52.1(4)

0.41(5)

0.00

300

DC/E3

33

–

0.39(5)

1.03

D₂²⁺/D3

14

–

1.10(5)

2.70

D₁³⁺/C3

53

–

0.35(5)

0.57

S1–2

5

D₂²⁺/I1

10

–

1.30(5)

2.93

D₁³⁺/H1

69

–

0.42(3)

0.51

S₂/G1

16

49.5(5)

0.50(5)

−0.26

S₁/F1

5

52.6(3)

0.40(5)

0.00

80

D₂²⁺/I2

10

–

1.17(6)

2.96

D₁³⁺/H2

72

–

0.40(4)

0.62

S₂/G2

14

48.5(5)

0.51(5)

−0.22

S₁/F2

4

51.0(3)

0.40(5)

0.10

300

DC/J3

19

–

0.44(4)

1.07

D₂²⁺/I3

11

–

1.12(3)

2.7

D₁³⁺/H3

70

–

0.35(4)

0.6

S1–2*

5

Sing1/N1

9

–

0.12(3)

–

D₁³⁺/M1

19

–

0.34(5)

1.68

S₂/L1

35

48.1(5)

0.27(8)

−0.07

S₁/K1

37

52.3(5)

0.46(6)

−0.18

80

Sing1/N2

50

–

0.26(3)

–

D₁³⁺/M2

5

–

0.39(5)

0.00

S₂/L2

19

48.0(7)

0.43(8)

−0.36

S₁/K2

26

52.3(7)

0.33(6)

0.07

300

D₁³⁺/M3

12

–

0.28(5)

0.00

DC/N3

63

–

0.21(3)

0.86

S₁/K3

25

49.76(3)

0.25(6)

−0.13

B

5

D₁³⁺/Q1

51

–

0.39(4)

1.37

S₂/P1

23

49.4(4)

0.32(3)

0.00

S₁/O1

26

53.0(5)

0.41(5)

0.00

80

DC/R2

8

–

0.38(3)

1.83

D₁³⁺/Q2

52

–

0.36(3)

1.01

S₂/P2

21

49.6(4)

0.35(3)

0.18

S₁/O2

19

53.0(5)

0.40(5)

−0.1

300

DC/R3

10

–

0.35(3)

1.8

D₁³⁺/Q3

48

–

0.34(3)

0.00

S₂/P3

22

27.0(3)

−0.13(3)

0.00

S₁/O3

20

48.8(5)

0.46(5)

0.00