Table 3 Parameters of the kinetic models for MB dye adsorption onto 50 mg AC500/NZ at 25 °C and pH 7.
Dye concentration (ppm) | 5 | 15 | 20 | 25 | 30 |
|---|---|---|---|---|---|
First-order kinetic model | |||||
K2 | 0.0829 | 0.0686 | 0.0605 | 0.0667 | 0.0783 |
qe | 1.6 | 2.8 | 3.2 | 4.2 | 4.9 |
R2 | 0.8763 | 0.8392 | 0.858 | 0.902 | 0.8316 |
qe exp | 9.92 | 29.10 | 37.20 | 44.25 | 51 |
Second-order kinetic model | |||||
K3 | 0.0891 | 0.0187 | 0.0126 | 0.0054 | 0.0036 |
qe | 10.10 | 29.58 | 37.73 | 46.29 | 54.64 |
R2 | 0.9996 | 0.9972 | 0.9965 | 0.9939 | 0.989 |
qe exp | 9.92 | 29.10 | 37.20 | 44.25 | 51 |
Elovich kinetic model | |||||
β (g/mg) | 1.5278 | 0.4219 | 0.3076 | 0.1472 | 0.1146 |
α (mg/min) | 53,234.23 | 8506.14 | 4629.45 | 83.88 | 55.05 |
R2 | 0.9842 | 0.9156 | 0.9552 | 0.9851 | 0.9697 |
Intraparticle diffusion kinetic model | |||||
K1 | 6.27 | 5.23 | 3.7 | 2.93 | 0.97 |
I | 11.75 | 11.94 | 14.71 | 12.07 | 4.55 |
R2 | 0.8905 | 0.8452 | 0.6593 | 0.6298 | 0.5706 |