Table 10 Variation of AC conductivity (σac) of the ligand, DBAPB, and its complexes 5, 12, 16, 20, 24, 27 with temperature, at frequency = 10 kHz.
T (k) | σac (ohm−1 cm−1) | ||||||
|---|---|---|---|---|---|---|---|
DBAPB | Mn(II) complex 12 | Co(II) complex 16 | Ni(II) complex 20 | Cu(II) complex 5 | Cu(II) complex 24 | Cu(II) complex 27 | |
308 | 3.14 × 10–5 | 1.17 × 10–5 | 2.78 × 10–5 | 3.31 × 10–6 | 2.64 × 10–5 | 2.00 × 10–5 | 7.29 × 10–6 |
318 | 3.56 × 10–4 | 1.24 × 10–5 | 2.93 × 10–5 | 3.35 × 10–6 | 2.67 × 10–5 | 2.04 × 10–5 | 7.52 × 10–6 |
328 | 4.77 × 10–4 | 9.83 × 10–5 | 3.50 × 10–4 | 3.62 × 10–6 | 2.70 × 10–5 | 2.13 × 10–5 | 8.93 × 10–6 |
338 | 5.02 × 10–4 | 1.59 × 10–4 | 5.86 × 10–4 | 3.73 × 10–6 | 2.96 × 10–5 | 6.52 × 10–4 | 1.07 × 10–5 |
348 | 6.66 × 10–4 | 2.50 × 10–4 | 9.98 × 10–4 | 3.79 × 10–6 | 8.38 × 10–5 | 7.09 × 10–4 | 1.14 × 10–5 |
358 | 1.03 × 10–3 | 2.70 × 10–4 | 1.51 × 10–3 | 4.01 × 10–6 | 9.81 × 10–5 | 2.56 × 10–3 | 1.22 × 10–5 |
368 | 1.61 × 10–3 | 3.54 × 10–4 | 1.54 × 10–3 | 5.38 × 10–6 | 1.11 × 10–4 | 5.81 × 10–3 | 1.34 × 10–5 |
378 | 2.95 × 10–3 | 4.52 × 10–4 | 1.98 × 10–3 | 1.14 × 10–5 | 1.58 × 10–4 | 7.27 × 10–3 | 1.68 × 10–5 |
388 | 4.72 × 10–3 | 4.53 × 10–4 | 4.22 × 10–3 | 2.38 × 10–5 | 2.45 × 10–4 | 8.95 × 10–3 | 1.88 × 10–5 |
398 | 7.29 × 10–3 | 4.75 × 10–4 | 8.15 × 10–3 | 4.61 × 10–4 | 2.47 × 10–4 | 4.93 × 10–2 | 6.22 × 10–5 |
408 | 1.57 × 10–2 | 4.95 × 10–3 | 1.42 × 10–2 | 8.46 × 10–4 | 3.45 × 10–4 | 5.24 × 10–2 | 1.24 × 10–4 |