Table 6 Evaluated bond angles of the ligand, DBAPB, and its metal complexes.
Compound/complex | Angle | Degree (°) | Angle | Degree (°) |
|---|---|---|---|---|
DBAPB | O(18)-C(17)-C(16) | 117.897 | H(35)-C(11)-N(18) | 120.193 |
O(18)-C(17)-C(12) | 122.838 | C(12)-C(11)-N(18) | 122.309 | |
O(19)-C(16)-C(17) | 120.947 | C(11)-N(18)-C(2) | 118.544 | |
O(19)-C(16)-C(15) | 119.206 | N(18)-C(2)-N(3) | 123.144 | |
1 | O(37)-Cr(11)-O(36) | 95.255 | O(36)-Cr(11)-O(7) | 101.394 |
O(37)-Cr(11)-Cl(35) | 77.647 | Cl(35)-Cr(11)-Cl(34) | 171.477 | |
O(37)-Cr(11)-Cl(34) | 96.775 | Cl(35)-Cr(11)-N(10) | 99.700 | |
O(37)-Cr(11)-N(10) | 82.222 | Cl(35)-Cr(11)-O(7) | 86.831 | |
O(37)-Cr(11)-O(7) | 155.625 | Cl(34)-Cr(11)-N(10) | 85.769 | |
O(36)-Cr(11)-Cl(35) | 82.856 | Cl(34)-Cr(11)-O(7) | 100.474 | |
O(36)-Cr(11)-Cl(34) | 91.332 | N(10)-Cr(11)-O(7) | 82.017 | |
O(36)-Cr(11)-N(10) | 175.894 | |||
2 | O(37)-Mn(33)-O(36) | 85.062 | O(36)-Mn(33)-O(7) | 81.294 |
O(37)-Mn(33)-O(35) | 81.083 | O(35)-Mn(33)-Cl(34) | 88.389 | |
O(37)-Mn(33)-Cl(34) | 163.987 | O(35)-Mn(33)-N(10) | 97.752 | |
O(37)-Mn(33)-N(10) | 91.566 | O(35)-Mn(33)-O(7) | 179.428 | |
O(37)-Mn(33)-O(7) | 99.067 | Cl(34)-Mn(33)-N(10) | 101.841 | |
O(36)-Mn(33)-O(35) | 98.175 | Cl(34)-Mn(33)-O(7) | 91.347 | |
O(36)-Mn(33)-Cl(34) | 84.531 | N(10)-Mn(33)-O(7) | 82.798 | |
O(36)-Mn(33)-N(10) | 162.997 | |||
3 | O(39)-Co(33)-O(37) | 87.790 | O(37)-Co(33)-O(7) | 82.044 |
O(39)-Co(33)-O(35) | 95.836 | O(35)-Co(33)-Cl(34) | 76.103 | |
O(39)-Co(33)-Cl(34) | 171.099 | O(35)-Co(33)-N(10) | 96.782 | |
O(39)-Co(33)-N(10) | 90.758 | O(35)-Co(33)-O(7) | 164.705 | |
O(39)-Co(33)-O(7) | 93.284 | Cl(34)-Co(33)-N(10) | 93.911 | |
O(37)-Co(33)-O(35) | 86.059 | Cl(34)-Co(33)-O(7) | 93.820 | |
O(37)-Co(33)-Cl(34) | 87.890 | O(37)-Co(33)-N(10) | 176.931 | |
4 | O(7)-Ni(33)-N(10) | 79.025 | Cl(34)-Ni(33)-O(36) | 94.9747 |
O(7)-Ni(33)-Cl(34) | 93.327 | Cl(34)-Ni(33)-O(37) | 90.0965 | |
O(7)-Ni(33)-O(36) | 94.134 | O(35)-Ni(33)-O(36) | 131.0844 | |
O(7)-Ni(33)-O(37) | 175.299 | O(35)-Ni(33)-O(37) | 78.7234 | |
N(10)-Ni(33)-O(35) | 96.564 | N(10)-Ni(33)-Cl(34) | 173.087 | |
N(10)-Ni(33)-O(36) | 165.251 | Cl(34)-Ni(33)-O(35) | 96.332 | |
N(10)-Ni(33)-O(37) | 84.668 | |||
5 | O (7)-Cu(33)-N(10) | 95.055 | O(7)-Cu(33)-O(37) | 80.729 |
O(7)-Cu(33)-O(34) | 163.051 | N(10)-Cu(33)-O(35) | 97.721 | |
O(7)-Cu(33)-O(35) | 134.238 | O(35)-Cu(33)-O(37) | 91.047 | |
N(1)-Zn(11)-O(10) | 93.815 | O(10)-Zn(11)-Cl(12) | 125.806 | |
6 | N(1)-Zn(11)-Cl(12) | 126.280 | O(10)-Zn(11)-O(35) | 121.355 |
N(1)-Zn(11)-O(35) | 102.508 | Cl(12)-Zn(11)-O(35) | 87.195 |
