Table 2 Equilibrium adsorption parameters for phenol removal by MSAC and pristine AC.
Model | MSAC | Pristine AC | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
Temperature (K) | Temperature (K) | |||||||||
298 | 313 | 328 | 343 | 358 | 298 | 313 | 328 | 343 | 358 | |
Langmuir | ||||||||||
qm (mg/g) | 145.71 | 135.62 | 131.09 | 120.94 | 120.31 | 116.604 | 117.274 | 118.547 | 111.827 | 111.973 |
KL (L/mg) | 0.0128 | 0.0103 | 0.0076 | 0.0062 | 0.0042 | 0.0062 | 0.0049 | 0.0039 | 0.0034 | 0.0026 |
R2 | 0.9986 | 0.9994 | 0.9986 | 0.9994 | 0.9989 | 0.9984 | 0.9989 | 0.9994 | 0.9997 | 0.9999 |
R2adj | 0.9982 | 0.9992 | 0.9981 | 0.9992 | 0.9986 | 0.9979 | 0.9986 | 0.9992 | 0.9996 | 0.9999 |
MSE (mg/g)2 | 0.941 | 0.329 | 0.667 | 0.223 | 0.331 | 0.529 | 0.336 | 0.165 | 0.076 | 0.019 |
Freundlich | ||||||||||
KF ((mg/g)(mg/L)−1/n) | 12.713 | 9.627 | 6.587 | 4.811 | 2.693 | 4.688 | 3.395 | 2.495 | 1.919 | 1.249 |
1/n (dimensionless) | 2.554 | 2.399 | 2.168 | 2.045 | 1.783 | 2.056 | 1.894 | 1.763 | 1.694 | 1.561 |
R2 | 0.9786 | 0.9796 | 0.9829 | 0.9827 | 0.9873 | 0.9911 | 0.9925 | 0.9929 | 0.9923 | 0.9938 |
R2adj | 0.9715 | 0.9729 | 0.9773 | 0.9769 | 0.9831 | 0.9882 | 0.9901 | 0.9905 | 0.9897 | 0.9917 |
MSE (mg/g)2 | 14.778 | 11.283 | 8.054 | 6.445 | 3.945 | 2.995 | 2.331 | 2.065 | 1.851 | 1.262 |
Tempkin | ||||||||||
KT (L/mg) | 76.173 | 79.876 | 81.173 | 87.464 | 90.389 | 92.349 | 92.928 | 93.986 | 101.142 | 107.134 |
bT (J/mol) | 0.12 | 0.091 | 0.066 | 0.053 | 0.038 | 0.055 | 0.045 | 0.038 | 0.033 | 0.028 |
R2 | 0.999 | 0.9998 | 0.9997 | 0.9999 | 0.9985 | 0.9969 | 0.9951 | 0.9936 | 0.9935 | 0.9913 |
R2adj | 0.9987 | 0.9998 | 0.9996 | 0.9999 | 0.9979 | 0.9959 | 0.9934 | 0.9915 | 0.9913 | 0.9884 |
MSE (mg/g)2 | 0.673 | 0.094 | 0.148 | 0.024 | 0.475 | 1.019 | 1.537 | 1.848 | 1.557 | 1.753 |