Table 7 Kinetics parameters of models on GA, OS400 and OSMG adsorbents.
Adsorbent | Conc.(ppm) | Pseudo first-order model | Pseudo second-order model | Intraparticle diffusion model | |||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
qe,1,cal (mg/g) | K1 (min-1) | R2 | qe,2,cal (mg/g) | K2 (g/mg min) | h (mg/g min) | R2 | Kint mg/g min-0.5 | C (mg/g) | R2 | ||
GA | 5 | 1.098 | 0.042 | 0.985 | 3.855 | 0.0144 | 0.215 | 0.996 | 0.3223 | 0.372 | 0.939 |
4 | 1.036 | 0.041 | 0.986 | 3.590 | 0.0114 | 0.147 | 0.993 | 0.2939 | 0.192 | 0.956 | |
3 | 0.939 | 0.048 | 0.991 | 3.066 | 0.0144 | 0.136 | 0.983 | 0.2556 | 0.184 | 0.924 | |
2 | 0.827 | 0.058 | 0.980 | 2.546 | 0.0185 | 0.120 | 0.961 | 0.2146 | 0.177 | 0.879 | |
1 | 0.249 | 0.089 | 0.966 | 1.292 | 0.1347 | 0.225 | 0.991 | 0.1112 | 0.299 | 0.736 | |
OS400 | 5 | 2.161 | 0.054 | 0.903 | 8.992 | 0.0036 | 0.297 | 0.979 | 0.7186 | 0.231 | 0.953 |
4 | 1.990 | 0.040 | 0.851 | 10.03 | 0.0013 | 0.133 | 0.957 | 0.6153 | -0.39 | 0.971 | |
3 | 1.621 | 0.035 | 0.901 | 8.445 | 0.0013 | 0.098 | 0.901 | 0.4892 | -0.34 | 0.957 | |
2 | 0.951 | 0.065 | 0.978 | 3.249 | 0.0463 | 0.489 | 0.997 | 0.2739 | 0.739 | 0.798 | |
1 | 0.489 | 0.103 | 0.997 | 1.675 | 0.1700 | 0.477 | 0.997 | 0.1395 | 0.480 | 0.697 | |
OSMG | 5 | 1.992 | 0.089 | 0.956 | 9.938 | 0.0358 | 3.544 | 0.999 | 0.7862 | 3.285 | 0.659 |
4 | 1.586 | 0.085 | 0.902 | 8.007 | 0.0586 | 3.761 | 0.999 | 0.6216 | 2.839 | 0.619 | |
3 | 1.371 | 0.107 | 0.881 | 5.907 | 0.1170 | 4.085 | 0.999 | 0.4512 | 2.230 | 0.580 | |
2 | 0.912 | 0.122 | 0.888 | 3.850 | 0.2530 | 3.751 | 0.999 | 0.2892 | 1.524 | 0.549 | |
1 | 0.587 | 0.219 | 0.812 | 1.812 | 1.0960 | 3.600 | 0.999 | 0.1349 | 0.746 | 0.520 | |