Table 7 Kinetics parameters of models on GA, OS400 and OSMG adsorbents.

From: Synthesis of activated carbon composited with Egyptian black sand for enhanced adsorption performance toward methylene blue dye

Adsorbent

Conc.(ppm)

Pseudo first-order model

Pseudo second-order model

Intraparticle diffusion model

qe,1,cal

(mg/g)

K1

(min-1)

R2

qe,2,cal

(mg/g)

K2

(g/mg min)

h

(mg/g min)

R2

Kint

mg/g min-0.5

C

(mg/g)

R2

GA

5

1.098

0.042

0.985

3.855

0.0144

0.215

0.996

0.3223

0.372

0.939

4

1.036

0.041

0.986

3.590

0.0114

0.147

0.993

0.2939

0.192

0.956

3

0.939

0.048

0.991

3.066

0.0144

0.136

0.983

0.2556

0.184

0.924

2

0.827

0.058

0.980

2.546

0.0185

0.120

0.961

0.2146

0.177

0.879

1

0.249

0.089

0.966

1.292

0.1347

0.225

0.991

0.1112

0.299

0.736

OS400

5

2.161

0.054

0.903

8.992

0.0036

0.297

0.979

0.7186

0.231

0.953

4

1.990

0.040

0.851

10.03

0.0013

0.133

0.957

0.6153

-0.39

0.971

3

1.621

0.035

0.901

8.445

0.0013

0.098

0.901

0.4892

-0.34

0.957

2

0.951

0.065

0.978

3.249

0.0463

0.489

0.997

0.2739

0.739

0.798

1

0.489

0.103

0.997

1.675

0.1700

0.477

0.997

0.1395

0.480

0.697

OSMG

5

1.992

0.089

0.956

9.938

0.0358

3.544

0.999

0.7862

3.285

0.659

4

1.586

0.085

0.902

8.007

0.0586

3.761

0.999

0.6216

2.839

0.619

3

1.371

0.107

0.881

5.907

0.1170

4.085

0.999

0.4512

2.230

0.580

2

0.912

0.122

0.888

3.850

0.2530

3.751

0.999

0.2892

1.524

0.549

1

0.587

0.219

0.812

1.812

1.0960

3.600

0.999

0.1349

0.746

0.520