Table 3 Rate coefficient (in cm3 molecule−1 s−1) for the BrO + HO2 reaction without and with one water molecule at different heights (h).
From: The influence of a single water molecule on the reaction of BrO + HO2
h (km)a | T (K)a | kCOMR1 Channel 1 | kCOMR2 Channel 2 | kCOMRW1 Channel 1W1 | kCOMRW2 Channel 1W2 | kCOMRW3 Channel 1W3 | kCOMRW4 Channel 1W4 |
|---|---|---|---|---|---|---|---|
0 | 298.15 | 1.44 × 10–11 | 2.62 × 10–21 | 1.29 × 10–17 | 1.99 × 10–21 | 3.83 × 10–16 | 1.98 × 10–21 |
0 | 288.19 | 1.66 × 10–11 | 1.67 × 10–21 | 1.12 × 10–17 | 1.33 × 10–21 | 4.16 × 10–16 | 1.11 × 10–21 |
2 | 275.21 | 2.03 × 10–11 | 8.90 × 10–22 | 9.12 × 10–18 | 7.61 × 10–22 | 4.72 × 10–16 | 4.89 × 10–22 |
4 | 262.23 | 2.55 × 10–11 | 4.42 × 10–22 | 7.30 × 10–18 | 4.11 × 10–22 | 5.38 × 10–16 | 2.00 × 10–22 |
6 | 249.25 | 3.28 × 10–11 | 2.06 × 10–23 | 5.73 × 10–18 | 2.09 × 10–22 | 6.26 × 10–16 | 7.47 × 10–23 |
8 | 236.27 | 2.36 × 10–11 | 8.84 × 10–23 | 4.40 × 10–18 | 9.87 × 10–23 | 7.45 × 10–16 | 2.51 × 10–23 |
10 | 223.29 | 3.60 × 10–11 | 3.46 × 10–23 | 3.27 × 10–18 | 4.28 × 10–23 | 9.00 × 10–16 | 7.44 × 10–24 |
12 | 216.69 | 7.16 × 10–11 | 2.05 × 10–23 | 2.79 × 10–18 | 2.30 × 10–23 | 1.01 × 10–15 | 3.80 × 10–24 |
