Table 4 Effective rate coefficients for the BrO + HO2 + H2O reaction at 216.69–298.15 K (cm3 molecule−1 s−1).
From: The influence of a single water molecule on the reaction of BrO + HO2
h (km)a | T (K)a | [H2O]b | \(k_{{\text{COMR}{1}}}^{^{\prime}}\) | \(k_{{\text{COMR}{2}}}^{^{\prime}}\) | \(k_{{\text{COMR}{3}}}^{^{\prime}}\) | \(k_{{\text{COMR}{4}}}^{^{\prime}}\) |
|---|---|---|---|---|---|---|
0 | 298.15 | 7.79 × 1017 | 8.52 × 10–21 | 7.55 × 10–27 | 8.14 × 10–21 | 3.90 × 10–26 |
0 | 288.19 | 4.34 × 1017 | 6.12 × 10–21 | 3.15 × 10–27 | 5.99 × 10–21 | 1.51 × 10–26 |
2 | 275.21 | 1.89 × 1017 | 3.79 × 10–21 | 9.22 × 10–28 | 3.74 × 10–21 | 3.96 × 10–27 |
4 | 262.23 | 7.43 × 1016 | 2.21 × 10–21 | 2.33 × 10–28 | 2.17 × 10–21 | 8.92 × 10–28 |
6 | 249.25 | 2.64 × 1016 | 1.21 × 10–21 | 5.13 × 10–29 | 1.19 × 10–21 | 1.72 × 10–28 |
8 | 236.27 | 8.15 × 1015 | 6.10 × 10–22 | 9.25 × 10–30 | 5.99 × 10–22 | 2.70 × 10–29 |
10 | 223.29 | 2.15 × 1015 | 2.78 × 10–22 | 1.34 × 10–30 | 2.71 × 10–22 | 3.36 × 10–30 |
12 | 216.69 | 1.01 × 1015 | 1.77 × 10–22 | 3.90 × 10–31 | 1.74 × 10–22 | 1.04 × 10–30 |
