Table 2 Bond lengths (Å) and bond-angles (°) for [NH₃(CH₂)₂NH₃]₂CdBr₄·2Br at 250 K, 300 K, and 350 K.

Cd-Br(1)

2.6130 (11)

2.6116 (15)

2.6109 (6)

Cd-Br(2)

2.7028 (11)

2.6981 (12)

2.6933 (6)

Cd-Br(3)

2.5737 (10)

2.5708 (9)

2.5685 (3)

Cd-Br(3-a)

2.5737 (10)

2.5707 (9)

2.5686 (3)

N(1)–C(1)

1.491 (4)

1.483 (4)

1.482 (5)

N(2)–C(2)

1.488 (3)

1.484 (3)

1.478 (4)

C(1)–C(2)

1.520 (4)

1.511 (4)

1.511 (5)

N–H

0.9000

0.9000

0.8900

C–H

0.9800

0.9800

0.9700

Br(3)-Cd-Br(3-a)

133.90 (3)

134.00 (3)

134.23 (2)

Br(1)-Cd-Br(3-a)

107.467 (14)

107.365 (16)

107.21 (11)

Br(3)-Cd-Br(1)

107.467 (13)

107.365 (16)

107.21 (11)

Br(2)-Cd-Br(3-a)

99.996 (13)

100.023 (15)

99.937 (12)

Br(1)-Cd-Br(2)

103.62 (2)

103.74 (3)

104.11 (2)

Br(3)-Cd-Br(2)

99.997 (13)

100.024 (15)

99.938 (12)