Table 6 Electrochemical kinetic variables from EIS studies for C-steel in 1.0 M HCl without and with different doses of the studied inhibitors at 298 K.
Inhibitor | EIS data | |||||||
|---|---|---|---|---|---|---|---|---|
Conc., M | Rct Ω cm2 | Yo,µΩ−1 sn cm−2 | n | Cdl μF cm2 | Θ | %ηEIS | Goodness of fit (χ2) | |
Blank | 30.6 ± 0.1753 | 306 | 0.849 | 161.4 ± 0.2122 | – | – | 15.71 × 10–3 | |
MA-1440 | 5 × 10–6 | 107.5 ± 0.1664 | 211 | 0.853 | 113.1 ± 0.1612 | 0.715 | 71.5 | 17.44 × 10–3 |
10 × 10–6 | 122.0 ± 0.2109 | 198 | 0.859 | 104.9 ± 0.1553 | 0.749 | 74.9 | 20.57 × 10–3 | |
15 × 10–6 | 135.5 ± 0.1632 | 187 | 0.859 | 97.2 ± 0.1762 | 0.774 | 77.4 | 19.11 × 10–3 | |
20 × 10–6 | 152.2 ± 0.1728 | 179 | 0.865 | 92.3 ± 0.1332 | 0.799 | 79.9 | 21.01 × 10–3 | |
25 × 10–6 | 170.9 ± 0.1543 | 170 | 0.874 | 88.2 ± 0.1751 | 0.821 | 82.1 | 16.33 × 10–3 | |
30 × 10–6 | 178.9 ± 0.2128 | 166 | 0.875 | 87.2 ± 0.2013 | 0.829 | 82.9 | 23.11 × 10–3 | |
MA-1456 | 5 × 10–6 | 91.1 ± 0.1745 | 219 | 0.887 | 139.1 ± 0.1743 | 0.664 | 66.4 | 16.16 × 10–3 |
10 × 10–6 | 99.1 ± 0.1453 | 214 | 0.888 | 131.6 ± 0.1451 | 0.691 | 69.1 | 13.61 × 10–3 | |
15 × 10–6 | 112.7 ± 0.1401 | 208 | 0.891 | 119.6 ± 0.1812 | 0.728 | 72.8 | 15.78 × 10–3 | |
20 × 10–6 | 127.6 ± 0.2024 | 193 | 0.896 | 108.0 ± 0.2109 | 0.760 | 76.0 | 18.87 × 10–3 | |
25 × 10–6 | 135.5 ± 0.1741 | 185 | 0.891 | 102.2 ± 0.2202 | 0.774 | 77.4 | 17.55 × 10–3 | |
30 × 10–6 | 141.1 ± 0.1224 | 180 | 0.899 | 98.8 ± 0.1913 | 0.783 | 78.3 | 16.22 × 10–3 | |